Imide Silanes: Adhesion promoters for polyimides

G. C. Tesoro, G. P. Rajendran, C. Park, D. R. Uhlmann

Research output: Contribution to journalArticle

8 Scopus citations

Abstract

The investigation of adhesion promoters prepared by the reaction of amino-functional silanes with dianhydrides (or diester-diacid chlorides) of tetracarboxylic aromatic acids is reported. The new coupling agents, designed to exhibit superior thermo-oxidative stability were applied under conditions determined from kinetic studies of hydrolysis and condensation reactions, and their coupling effectiveness for polyimides was evaluated by peel tests. For a wholly aromatic imide silane (CA-25), adhesion retention after prolonged exposure to elevated temperature was far greater than obtained with adhesion promoters previously evaluated in polyimide systems.

Original languageEnglish (US)
Pages (from-to)39-51
Number of pages13
JournalJournal of Adhesion Science and Technology
Volume1
Issue number1
DOIs
StatePublished - Jan 1 1987
Externally publishedYes

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Keywords

  • Silanes
  • adhesion
  • interface
  • polyimides
  • thermo-oxidative stability

ASJC Scopus subject areas

  • Chemistry(all)
  • Mechanics of Materials
  • Surfaces and Interfaces
  • Surfaces, Coatings and Films
  • Materials Chemistry

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