IMIDE SILANES: ADHESION PROMOTERS FOR POLYIMIDES.

G. C. Tesoro, G. P. Rajendran, C. Park, Donald R Uhlmann

Research output: Contribution to journalArticle

8 Citations (Scopus)

Abstract

The investigation of adhesion promoters prepared by the reaction of amino-functional silanes with dianhydrides (or diester-diacid chlorides) of tetracarboxylic aromatic acids is reported. The new coupling agents, designed to exhibit superior thermo-oxidative stability were applied under conditions determined from kinetic studies of hydrolysis and condensation reactions, and their coupling effectiveness for polyimides was evaluated by peel tests. For a wholly aromatic imide silane (CA-25), adhesion retention after prolonged exposure to elevated temperature was far greater than obtained with adhesion promoters previously evaluated in polyimide systems.

Original languageEnglish (US)
Pages (from-to)39-51
Number of pages13
JournalJournal of Adhesion Science and Technology
Volume1
Issue number1
StatePublished - 1987
Externally publishedYes

Fingerprint

Imides
Silanes
imides
polyimides
Polyimides
silanes
adhesion
Adhesion
Condensation reactions
Coupling agents
Carboxylic acids
hydrolysis
Chlorides
Hydrolysis
thermal stability
condensation
chlorides
acids
Kinetics
kinetics

ASJC Scopus subject areas

  • Chemical Engineering(all)
  • Computational Mechanics
  • Mechanics of Materials
  • Materials Science(all)

Cite this

IMIDE SILANES : ADHESION PROMOTERS FOR POLYIMIDES. / Tesoro, G. C.; Rajendran, G. P.; Park, C.; Uhlmann, Donald R.

In: Journal of Adhesion Science and Technology, Vol. 1, No. 1, 1987, p. 39-51.

Research output: Contribution to journalArticle

Tesoro, GC, Rajendran, GP, Park, C & Uhlmann, DR 1987, 'IMIDE SILANES: ADHESION PROMOTERS FOR POLYIMIDES.', Journal of Adhesion Science and Technology, vol. 1, no. 1, pp. 39-51.
Tesoro, G. C. ; Rajendran, G. P. ; Park, C. ; Uhlmann, Donald R. / IMIDE SILANES : ADHESION PROMOTERS FOR POLYIMIDES. In: Journal of Adhesion Science and Technology. 1987 ; Vol. 1, No. 1. pp. 39-51.
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