IN SITU FT-IR SPECTROSCOPY OF THE ADSORPTION OF CO ON METHANOL CATALYSTS.

J. F. Edwards, Glenn L Schrader

Research output: Contribution to journalArticle

22 Citations (Scopus)

Abstract

Fourier transform infrared spectroscopy was used to identify surface species on zinc oxide and a zinc-copper mixed oxide at CO pressures up to 50 atm and a temperature of 200 degree C. In situ spectra were recorded in a high-pressure cell having a short path length. Spectra of adsorbed species on both oxides indicated the presence of carbonate, carboxylate, hydride, hydroxide, and formate surface species. The spectrum of the mixed oxide at 50 atm had additional bands which were assigned to a methoxide surface species.

Original languageEnglish (US)
Pages (from-to)559-563
Number of pages5
JournalApplied Spectroscopy
Volume35
Issue number6
StatePublished - Nov 1981
Externally publishedYes

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Carbon Monoxide
Oxides
Methanol
Infrared spectroscopy
formic acid
methyl alcohol
mixed oxides
Adsorption
catalysts
Catalysts
adsorption
spectroscopy
Zinc Oxide
Carbonates
formates
copper oxides
Zinc oxide
Hydrides
zinc oxides
carboxylates

ASJC Scopus subject areas

  • Spectroscopy
  • Instrumentation

Cite this

IN SITU FT-IR SPECTROSCOPY OF THE ADSORPTION OF CO ON METHANOL CATALYSTS. / Edwards, J. F.; Schrader, Glenn L.

In: Applied Spectroscopy, Vol. 35, No. 6, 11.1981, p. 559-563.

Research output: Contribution to journalArticle

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