A bidentate formate species adsorbed on a zinc site was a common intermediate in the water-gas shift and methanol synthesis reactions on Cu/ZnO catalysts. Adsorbed formaldehyde and methoxy species were identified as additional intermediates in the reaction pathway for methanol synthesis. An adsorbed carbonyl species on a reduced copper site was an activating agent for the reduction of formate groups to formaldehyde and methoxy species at 200°C.
|Original language||English (US)|
|Number of pages||5|
|Journal||Journal of physical chemistry|
|State||Published - Dec 1 1984|
ASJC Scopus subject areas
- Physical and Theoretical Chemistry