Interaction of perchloroethylene with cerium oxide in three-way catalysts

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Abstract

The role of cerium oxide on direct oxidation of perchloroethylene (PCE) by a three-way catalyst was explored. In the absence of an external oxidizing agent, PCE was oxidized over an alumina supported Pt/Rh three-way catalyst. We hypothesize that the chlorine atoms in the adsorbed PCE interact with oxygen in CeO2, reducing the cerium to create CeCl3.

Original languageEnglish (US)
Pages (from-to)153-158
Number of pages6
JournalCatalysis Letters
Volume132
Issue number1-2
DOIs
Publication statusPublished - Sep 2009

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Keywords

  • Cerium oxide
  • Perchloroethylene
  • Reactive adsorption
  • Three-way catalyst

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)

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