Interface between C60 and Ag on nanostructured plasmonic Ag gratings: A sers study

Akram A. Khosroabadi, Dallas L. Matz, Palash Gangopadhyay, Jeanne E. Pemberton, Robert A. Norwood

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Abstract

Nanostructured electrodes and interfaces can enhance light absorption in organic solar cells due to efficient light harvesting. Ultrathin films of an active layer (C60) deposited on nanostructured grating electrodes show more absorption as a result of increased light trapping. Plasmonic nanostructured electrodes with various geometries and dimensions have been fabricated on printed polyacrylonitrile (PAN) and subsequently characterized. Surface enhanced Raman scattering (SERS) measurements show significant signal enhancement (over two orders of magnitude) on nanostructured samples when compared to planar Ag substrates due to local electromagnetic field enhancement. Furthermore, conversion of PAN to graphitic carbon is evidenced in SERS spectra. The surface area was determined using underpotential deposition (UPD) of thallium and agrees with the geometric surface area calculated from SEM images. The FDTD simulated electric field distribution inside the samples confirms the experimental results. A 60 fold increase in the electric field results in three to four orders of magnitude enhancement in the SERS signal depending on the dimensions of the pillars and gratings. Further study of the interaction between a top organic layer (C60) and the Ag electrode will help us to understand the nanoscale charge transfer rate critical to optimization and design of efficient organic solar cells.

Original languageEnglish (US)
Title of host publicationPlasmonics
Subtitle of host publicationMetallic Nanostructures and Their Optical Properties XI
PublisherSPIE
ISBN (Print)9780819496591
DOIs
StatePublished - Jan 1 2013
EventPlasmonics: Metallic Nanostructures and Their Optical Properties XI - San Diego, CA, United States
Duration: Aug 25 2013Aug 29 2013

Publication series

NameProceedings of SPIE - The International Society for Optical Engineering
Volume8809
ISSN (Print)0277-786X
ISSN (Electronic)1996-756X

Other

OtherPlasmonics: Metallic Nanostructures and Their Optical Properties XI
CountryUnited States
CitySan Diego, CA
Period8/25/138/29/13

Keywords

  • Ag nanostructures
  • SERS
  • metal/organic interface

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Condensed Matter Physics
  • Computer Science Applications
  • Applied Mathematics
  • Electrical and Electronic Engineering

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  • Cite this

    Khosroabadi, A. A., Matz, D. L., Gangopadhyay, P., Pemberton, J. E., & Norwood, R. A. (2013). Interface between C60 and Ag on nanostructured plasmonic Ag gratings: A sers study. In Plasmonics: Metallic Nanostructures and Their Optical Properties XI [88091L] (Proceedings of SPIE - The International Society for Optical Engineering; Vol. 8809). SPIE. https://doi.org/10.1117/12.2024333