Interface evolution in the formation of low work function metal ohmic contacts on organic layers in photonic devices

Jeanne E Pemberton, Dallas L. Matz, Matthew C. Schalnat, Cynthia L. Shaw

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Abstract

Low work function metals are commonly used as electron-selective ohmic contacts with electron transport layers in molecular photonic and electronic devices such as organic photovoltaics (OPVs), organic light emitting diodes (OLEDs) and organic field effect transistors (OFETs). Although the fundamental charge injection physics of such interfaces have been well described, the interfacial chemistry associated with these contacts is poorly understood and characterized. Efforts to characterize the chemistry of such interfaces using surface Raman spectroscopy have been undertaken in this laboratory. In this presentation, chemistry associated with evolution of the interfaces in these ohmic contacts will be explored for the low work function metals Ag, Al, Ca and Mg with solid state organic thin films including simple organic model systems, ordered forms of carbon, and polymeric systems. Implications for device performance will be considered.

Original languageEnglish (US)
Title of host publicationACS National Meeting Book of Abstracts
StatePublished - 2011
Event241st ACS National Meeting and Exposition - Anaheim, CA, United States
Duration: Mar 27 2011Mar 31 2011

Other

Other241st ACS National Meeting and Exposition
CountryUnited States
CityAnaheim, CA
Period3/27/113/31/11

Fingerprint

Photonic devices
Ohmic contacts
Metals
Organic field effect transistors
Charge injection
Organic light emitting diodes (OLED)
Surface chemistry
Photonics
Raman spectroscopy
Carbon
Physics
Thin films
Electrons
Electron Transport

ASJC Scopus subject areas

  • Chemistry(all)
  • Chemical Engineering(all)

Cite this

Pemberton, J. E., Matz, D. L., Schalnat, M. C., & Shaw, C. L. (2011). Interface evolution in the formation of low work function metal ohmic contacts on organic layers in photonic devices. In ACS National Meeting Book of Abstracts

Interface evolution in the formation of low work function metal ohmic contacts on organic layers in photonic devices. / Pemberton, Jeanne E; Matz, Dallas L.; Schalnat, Matthew C.; Shaw, Cynthia L.

ACS National Meeting Book of Abstracts. 2011.

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Pemberton, JE, Matz, DL, Schalnat, MC & Shaw, CL 2011, Interface evolution in the formation of low work function metal ohmic contacts on organic layers in photonic devices. in ACS National Meeting Book of Abstracts. 241st ACS National Meeting and Exposition, Anaheim, CA, United States, 3/27/11.
Pemberton, Jeanne E ; Matz, Dallas L. ; Schalnat, Matthew C. ; Shaw, Cynthia L. / Interface evolution in the formation of low work function metal ohmic contacts on organic layers in photonic devices. ACS National Meeting Book of Abstracts. 2011.
@inproceedings{cc45eda2ae5848e694ca2e49a1cefcd2,
title = "Interface evolution in the formation of low work function metal ohmic contacts on organic layers in photonic devices",
abstract = "Low work function metals are commonly used as electron-selective ohmic contacts with electron transport layers in molecular photonic and electronic devices such as organic photovoltaics (OPVs), organic light emitting diodes (OLEDs) and organic field effect transistors (OFETs). Although the fundamental charge injection physics of such interfaces have been well described, the interfacial chemistry associated with these contacts is poorly understood and characterized. Efforts to characterize the chemistry of such interfaces using surface Raman spectroscopy have been undertaken in this laboratory. In this presentation, chemistry associated with evolution of the interfaces in these ohmic contacts will be explored for the low work function metals Ag, Al, Ca and Mg with solid state organic thin films including simple organic model systems, ordered forms of carbon, and polymeric systems. Implications for device performance will be considered.",
author = "Pemberton, {Jeanne E} and Matz, {Dallas L.} and Schalnat, {Matthew C.} and Shaw, {Cynthia L.}",
year = "2011",
language = "English (US)",
booktitle = "ACS National Meeting Book of Abstracts",

}

TY - GEN

T1 - Interface evolution in the formation of low work function metal ohmic contacts on organic layers in photonic devices

AU - Pemberton, Jeanne E

AU - Matz, Dallas L.

AU - Schalnat, Matthew C.

AU - Shaw, Cynthia L.

PY - 2011

Y1 - 2011

N2 - Low work function metals are commonly used as electron-selective ohmic contacts with electron transport layers in molecular photonic and electronic devices such as organic photovoltaics (OPVs), organic light emitting diodes (OLEDs) and organic field effect transistors (OFETs). Although the fundamental charge injection physics of such interfaces have been well described, the interfacial chemistry associated with these contacts is poorly understood and characterized. Efforts to characterize the chemistry of such interfaces using surface Raman spectroscopy have been undertaken in this laboratory. In this presentation, chemistry associated with evolution of the interfaces in these ohmic contacts will be explored for the low work function metals Ag, Al, Ca and Mg with solid state organic thin films including simple organic model systems, ordered forms of carbon, and polymeric systems. Implications for device performance will be considered.

AB - Low work function metals are commonly used as electron-selective ohmic contacts with electron transport layers in molecular photonic and electronic devices such as organic photovoltaics (OPVs), organic light emitting diodes (OLEDs) and organic field effect transistors (OFETs). Although the fundamental charge injection physics of such interfaces have been well described, the interfacial chemistry associated with these contacts is poorly understood and characterized. Efforts to characterize the chemistry of such interfaces using surface Raman spectroscopy have been undertaken in this laboratory. In this presentation, chemistry associated with evolution of the interfaces in these ohmic contacts will be explored for the low work function metals Ag, Al, Ca and Mg with solid state organic thin films including simple organic model systems, ordered forms of carbon, and polymeric systems. Implications for device performance will be considered.

UR - http://www.scopus.com/inward/record.url?scp=80051911038&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=80051911038&partnerID=8YFLogxK

M3 - Conference contribution

BT - ACS National Meeting Book of Abstracts

ER -