Isolation and characterization of the molybdenum alkylidyne complex [(F3C)Me2CO]2Mo(C-t-Bu)[N(Ar)P=C(H)(CMe 2Ph)] and its conversion to a phosphamolybdacyclobutene

Gregory M. Jamison, Randall S. Saunders, David R. Wheeler, Todd M. Alam, Mark D. McClain, Douglas A. Loy, Joseph W. Ziller

Research output: Contribution to journalArticle

13 Scopus citations

Abstract

Novel molybdenum alkylidyne [(F3C)Me2-CO]2Mo(C-t-Bu)[N(Ar)P=C(H)(CMe 2Ph)] (Ar = 2,6-(i-Pr)2C6H3; 3b) is formed in the reaction of tert-butylphosphaalkyne 2 with molybdenum alkylidene 1b. Alkylidyne 3b, which contains a formal (phosphaalkenyl)amido ligand, rearranges quantitatively at elevated temperature to form the alkoxide-shifted phosphamolybdacyclobutene 4b. Complexes 36 and 4b have been fully characterized by spectroscopic and X-ray crystallographic analysis; cleavage of the P≡C-t-Bu triple bond in complex 3b is confirmed.

Original languageEnglish (US)
Pages (from-to)3244-3246
Number of pages3
JournalOrganometallics
Volume15
Issue number15
StatePublished - Jul 23 1996
Externally publishedYes

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry

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