Isolation of [{HB(Me2pz)3}MoO2(OC6H4S)]2, a binuclear Mo(VI) complex containing a disulfide bond

Sue A Roberts, Gary P. Darsey, W. E. Cleland, John H. Enemark

Research output: Contribution to journalArticle

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Abstract

Aerial recrystallization of the mononuclear molybdenum(V) complex {HB(Me2pz)3}MoO(OC6H4-o-S) produced the novel binuclear Mo(VI) complex [{HB(Me2pz)3}MoO2(OC6H4- o-S)]2 which contains a disulfide bond. The dimer crystallizes as the dioxane solvate in the space group C2/c with cell parameters a=23.46(2), b=11.100(4), c=21.571(8) Å, β=104.23(4)°, Z=4. Final Rw=0.062 (2236 reflections with Fo>3σ(Fo), 301 variable parameters). The dimer contains two crystallographically identical distorted octahedral MoO22+ centers. One face of each octahedron is occupied by two oxo ligands and a phenolate oxygen atom; the opposite face is occupied by three nitrogens of the HB(Me2pz)3- ligand. The two Mo(VI) centers of the dimers are linked by a disulfide bond formed upon oxidation of the 2-mercaptophenolate ligand of the original molybdenum(V) compound.

Original languageEnglish (US)
Pages (from-to)95-97
Number of pages3
JournalInorganica Chimica Acta
Volume154
Issue number1
DOIs
StatePublished - Dec 1 1988

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disulfides
Disulfides
Dimers
isolation
Molybdenum
Ligands
dimers
ligands
molybdenum
oxygen atoms
Nitrogen
Antennas
Oxygen
nitrogen
Atoms
Oxidation
oxidation
cells
molybdenum dioxide

ASJC Scopus subject areas

  • Biochemistry
  • Inorganic Chemistry
  • Physical and Theoretical Chemistry
  • Materials Chemistry

Cite this

Isolation of [{HB(Me2pz)3}MoO2(OC6H4S)]2, a binuclear Mo(VI) complex containing a disulfide bond. / Roberts, Sue A; Darsey, Gary P.; Cleland, W. E.; Enemark, John H.

In: Inorganica Chimica Acta, Vol. 154, No. 1, 01.12.1988, p. 95-97.

Research output: Contribution to journalArticle

Roberts, Sue A ; Darsey, Gary P. ; Cleland, W. E. ; Enemark, John H. / Isolation of [{HB(Me2pz)3}MoO2(OC6H4S)]2, a binuclear Mo(VI) complex containing a disulfide bond. In: Inorganica Chimica Acta. 1988 ; Vol. 154, No. 1. pp. 95-97.
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