K-metasomatism and detachment-related mineralization, Harcuvar Mountains, Arizona

Michael S. Roddy, Stephen J. Reynolds, Brian M. Smith, Joaquin Ruiz

Research output: Contribution to journalArticle

51 Citations (Scopus)

Abstract

The Bullard detachment fault, a regional low-angle normal fault exposed in the Harcuvar Mountains of west-central Arizona, separates lower-plate mylonitic rocks and chloritic breccia from upper-plate volcanic and sedimentary rocks. Areally extensive K-metasomatism has converted upper-plate mafic flows and felsic ash-flow tuffs into rocks with 8 to 12 wt. % K2O, <0.4 wt. % Na2O, and a simple K-feldspar-hematite-quartz mineralogy. The secondary K-feldspar is very pure (Or 95 to 99.5), monoclinic, and structurally similar to orthoclase. Differences in δ18O values between secondary K-feldspar replacing sanidine phenocrysts (9‰ to 11‰) and K-feldspar replacing groundmass (11‰ to 14‰) in the tuffs imply differential O-exchange with migrating fluids. Whole-rock δ18O values for tuffs (10‰ to 14‰) and mafic flows (6‰ to 9‰) do not, therefore, represent primary igneous values. The rocks apparently became K-metasomatized and 18O-enriched while interacting with low- to moderate-temperature, neutral to alkaline, oxidizing brines that accumulated in an extensional basin above the detachment fault. Cu-Au-Ag mineralization is concentrated in faults and fissures in metasomatized mafic flows above the detachment fault. Fluid-inclusion studies show that mineralizing fluids had minimum temperatures of 290 to 330 °C along the detachment fault, 240 to 290 °C in mafic flows above the detachment fault, and 100 to 130 °C in barite-calcite-Mn-oxide veins farther from the detachment fault. The predominant mineralizing fluids near the detachment fault and in the mafic flows were saline brines with 13 to 17 equivalent wt.% NaCI More dilute brines with 6 to 12 equivalent wt. % NaCI formed the barite-calcite-Mn-oxide veins. Inferred δ18O values of the mineralizing fluids range from +3‰ for high-temperature quartz-sulfide veins to -5‰ for lower-temperature barite-calcite-Mn-oxide veins. The high salinities, oxygen isotope compositions, and geologic setting indicate that the mineralizing fluids were basinal brines. The mineralizing fluids apparently evolved from early deep-level, reducing basin brines to a later stage marked by the influx of higher-level, oxidizing basin brines. Relatively minor amounts of less evolved, lower-18O meteoric water entered the system during the very late stages of mineralization. Paragenetic relations and geochemical and isotopic data indicate that mineralization was superimposed on previously K-metasomatized rocks. Mineralization and K-metasomatism may be indirectly linked, however, because both occurred during detachment faulting and both involved basinal brines. Specifically, K-metasomatism of upper-plate units liberated elements, such as Cu, Pb, Zn, Mn, Sr, and Na, that were incorporated into the mineralizing basin brines. Multiple fluid regimes during detachment faulting are indicated, because basin-brine-dominated mineralization overprinted lower-plate mylonitic rocks and breccia that had probably previously equilibrated with igneous or metamorphic fluids at deeper levels of the detachment system.

Original languageEnglish (US)
Pages (from-to)1627-1639
Number of pages13
JournalBulletin of the Geological Society of America
Volume100
Issue number10
DOIs
StatePublished - 1988

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detachment fault
metasomatism
mineralization
mountain
fluid
feldspar
barite
rock
basin
calcite
oxide
breccia
faulting
quartz
orthoclase
sanidine
ash flow
meteoric water
fissure
hematite

ASJC Scopus subject areas

  • Geology

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K-metasomatism and detachment-related mineralization, Harcuvar Mountains, Arizona. / Roddy, Michael S.; Reynolds, Stephen J.; Smith, Brian M.; Ruiz, Joaquin.

In: Bulletin of the Geological Society of America, Vol. 100, No. 10, 1988, p. 1627-1639.

Research output: Contribution to journalArticle

Roddy, Michael S. ; Reynolds, Stephen J. ; Smith, Brian M. ; Ruiz, Joaquin. / K-metasomatism and detachment-related mineralization, Harcuvar Mountains, Arizona. In: Bulletin of the Geological Society of America. 1988 ; Vol. 100, No. 10. pp. 1627-1639.
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abstract = "The Bullard detachment fault, a regional low-angle normal fault exposed in the Harcuvar Mountains of west-central Arizona, separates lower-plate mylonitic rocks and chloritic breccia from upper-plate volcanic and sedimentary rocks. Areally extensive K-metasomatism has converted upper-plate mafic flows and felsic ash-flow tuffs into rocks with 8 to 12 wt. {\%} K2O, <0.4 wt. {\%} Na2O, and a simple K-feldspar-hematite-quartz mineralogy. The secondary K-feldspar is very pure (Or 95 to 99.5), monoclinic, and structurally similar to orthoclase. Differences in δ18O values between secondary K-feldspar replacing sanidine phenocrysts (9‰ to 11‰) and K-feldspar replacing groundmass (11‰ to 14‰) in the tuffs imply differential O-exchange with migrating fluids. Whole-rock δ18O values for tuffs (10‰ to 14‰) and mafic flows (6‰ to 9‰) do not, therefore, represent primary igneous values. The rocks apparently became K-metasomatized and 18O-enriched while interacting with low- to moderate-temperature, neutral to alkaline, oxidizing brines that accumulated in an extensional basin above the detachment fault. Cu-Au-Ag mineralization is concentrated in faults and fissures in metasomatized mafic flows above the detachment fault. Fluid-inclusion studies show that mineralizing fluids had minimum temperatures of 290 to 330 °C along the detachment fault, 240 to 290 °C in mafic flows above the detachment fault, and 100 to 130 °C in barite-calcite-Mn-oxide veins farther from the detachment fault. The predominant mineralizing fluids near the detachment fault and in the mafic flows were saline brines with 13 to 17 equivalent wt.{\%} NaCI More dilute brines with 6 to 12 equivalent wt. {\%} NaCI formed the barite-calcite-Mn-oxide veins. Inferred δ18O values of the mineralizing fluids range from +3‰ for high-temperature quartz-sulfide veins to -5‰ for lower-temperature barite-calcite-Mn-oxide veins. The high salinities, oxygen isotope compositions, and geologic setting indicate that the mineralizing fluids were basinal brines. The mineralizing fluids apparently evolved from early deep-level, reducing basin brines to a later stage marked by the influx of higher-level, oxidizing basin brines. Relatively minor amounts of less evolved, lower-18O meteoric water entered the system during the very late stages of mineralization. Paragenetic relations and geochemical and isotopic data indicate that mineralization was superimposed on previously K-metasomatized rocks. Mineralization and K-metasomatism may be indirectly linked, however, because both occurred during detachment faulting and both involved basinal brines. Specifically, K-metasomatism of upper-plate units liberated elements, such as Cu, Pb, Zn, Mn, Sr, and Na, that were incorporated into the mineralizing basin brines. Multiple fluid regimes during detachment faulting are indicated, because basin-brine-dominated mineralization overprinted lower-plate mylonitic rocks and breccia that had probably previously equilibrated with igneous or metamorphic fluids at deeper levels of the detachment system.",
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T1 - K-metasomatism and detachment-related mineralization, Harcuvar Mountains, Arizona

AU - Roddy, Michael S.

AU - Reynolds, Stephen J.

AU - Smith, Brian M.

AU - Ruiz, Joaquin

PY - 1988

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N2 - The Bullard detachment fault, a regional low-angle normal fault exposed in the Harcuvar Mountains of west-central Arizona, separates lower-plate mylonitic rocks and chloritic breccia from upper-plate volcanic and sedimentary rocks. Areally extensive K-metasomatism has converted upper-plate mafic flows and felsic ash-flow tuffs into rocks with 8 to 12 wt. % K2O, <0.4 wt. % Na2O, and a simple K-feldspar-hematite-quartz mineralogy. The secondary K-feldspar is very pure (Or 95 to 99.5), monoclinic, and structurally similar to orthoclase. Differences in δ18O values between secondary K-feldspar replacing sanidine phenocrysts (9‰ to 11‰) and K-feldspar replacing groundmass (11‰ to 14‰) in the tuffs imply differential O-exchange with migrating fluids. Whole-rock δ18O values for tuffs (10‰ to 14‰) and mafic flows (6‰ to 9‰) do not, therefore, represent primary igneous values. The rocks apparently became K-metasomatized and 18O-enriched while interacting with low- to moderate-temperature, neutral to alkaline, oxidizing brines that accumulated in an extensional basin above the detachment fault. Cu-Au-Ag mineralization is concentrated in faults and fissures in metasomatized mafic flows above the detachment fault. Fluid-inclusion studies show that mineralizing fluids had minimum temperatures of 290 to 330 °C along the detachment fault, 240 to 290 °C in mafic flows above the detachment fault, and 100 to 130 °C in barite-calcite-Mn-oxide veins farther from the detachment fault. The predominant mineralizing fluids near the detachment fault and in the mafic flows were saline brines with 13 to 17 equivalent wt.% NaCI More dilute brines with 6 to 12 equivalent wt. % NaCI formed the barite-calcite-Mn-oxide veins. Inferred δ18O values of the mineralizing fluids range from +3‰ for high-temperature quartz-sulfide veins to -5‰ for lower-temperature barite-calcite-Mn-oxide veins. The high salinities, oxygen isotope compositions, and geologic setting indicate that the mineralizing fluids were basinal brines. The mineralizing fluids apparently evolved from early deep-level, reducing basin brines to a later stage marked by the influx of higher-level, oxidizing basin brines. Relatively minor amounts of less evolved, lower-18O meteoric water entered the system during the very late stages of mineralization. Paragenetic relations and geochemical and isotopic data indicate that mineralization was superimposed on previously K-metasomatized rocks. Mineralization and K-metasomatism may be indirectly linked, however, because both occurred during detachment faulting and both involved basinal brines. Specifically, K-metasomatism of upper-plate units liberated elements, such as Cu, Pb, Zn, Mn, Sr, and Na, that were incorporated into the mineralizing basin brines. Multiple fluid regimes during detachment faulting are indicated, because basin-brine-dominated mineralization overprinted lower-plate mylonitic rocks and breccia that had probably previously equilibrated with igneous or metamorphic fluids at deeper levels of the detachment system.

AB - The Bullard detachment fault, a regional low-angle normal fault exposed in the Harcuvar Mountains of west-central Arizona, separates lower-plate mylonitic rocks and chloritic breccia from upper-plate volcanic and sedimentary rocks. Areally extensive K-metasomatism has converted upper-plate mafic flows and felsic ash-flow tuffs into rocks with 8 to 12 wt. % K2O, <0.4 wt. % Na2O, and a simple K-feldspar-hematite-quartz mineralogy. The secondary K-feldspar is very pure (Or 95 to 99.5), monoclinic, and structurally similar to orthoclase. Differences in δ18O values between secondary K-feldspar replacing sanidine phenocrysts (9‰ to 11‰) and K-feldspar replacing groundmass (11‰ to 14‰) in the tuffs imply differential O-exchange with migrating fluids. Whole-rock δ18O values for tuffs (10‰ to 14‰) and mafic flows (6‰ to 9‰) do not, therefore, represent primary igneous values. The rocks apparently became K-metasomatized and 18O-enriched while interacting with low- to moderate-temperature, neutral to alkaline, oxidizing brines that accumulated in an extensional basin above the detachment fault. Cu-Au-Ag mineralization is concentrated in faults and fissures in metasomatized mafic flows above the detachment fault. Fluid-inclusion studies show that mineralizing fluids had minimum temperatures of 290 to 330 °C along the detachment fault, 240 to 290 °C in mafic flows above the detachment fault, and 100 to 130 °C in barite-calcite-Mn-oxide veins farther from the detachment fault. The predominant mineralizing fluids near the detachment fault and in the mafic flows were saline brines with 13 to 17 equivalent wt.% NaCI More dilute brines with 6 to 12 equivalent wt. % NaCI formed the barite-calcite-Mn-oxide veins. Inferred δ18O values of the mineralizing fluids range from +3‰ for high-temperature quartz-sulfide veins to -5‰ for lower-temperature barite-calcite-Mn-oxide veins. The high salinities, oxygen isotope compositions, and geologic setting indicate that the mineralizing fluids were basinal brines. The mineralizing fluids apparently evolved from early deep-level, reducing basin brines to a later stage marked by the influx of higher-level, oxidizing basin brines. Relatively minor amounts of less evolved, lower-18O meteoric water entered the system during the very late stages of mineralization. Paragenetic relations and geochemical and isotopic data indicate that mineralization was superimposed on previously K-metasomatized rocks. Mineralization and K-metasomatism may be indirectly linked, however, because both occurred during detachment faulting and both involved basinal brines. Specifically, K-metasomatism of upper-plate units liberated elements, such as Cu, Pb, Zn, Mn, Sr, and Na, that were incorporated into the mineralizing basin brines. Multiple fluid regimes during detachment faulting are indicated, because basin-brine-dominated mineralization overprinted lower-plate mylonitic rocks and breccia that had probably previously equilibrated with igneous or metamorphic fluids at deeper levels of the detachment system.

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