Kinetics and mechanism of reductive dehalogenation of carbon tetrachloride using zero-valence metals

Kara D. Warren, Robert G. Arnold, Tammie L. Bishop, Larson C. Lindholm, Eric A. Betterton

Research output: Contribution to journalArticle

81 Scopus citations

Abstract

Elemental iron and zinc reduced part-per-thousand levels of aqueous-phase carbon tetrachloride to chloroform in a few hours. Free metal ions, chloride ion and hydrogen gas were produced in the reaction; protons were consumed. Process kinetics were dependent on solution pH, surface area of the elemental metal, carbon tetrachloride concentration, buffer selection and solvent composition (volume fraction 2-propanol). Reaction rate was first-order with respect to carbon tetrachloride at concentrations less than 7.5 mM. This class of reactions offers promise as a means for initiating the destruction of heavily halogenated organic compounds.

Original languageEnglish (US)
Pages (from-to)217-227
Number of pages11
JournalJournal of Hazardous Materials
Volume41
Issue number2-3
DOIs
StatePublished - May 1995

ASJC Scopus subject areas

  • Environmental Engineering
  • Environmental Chemistry
  • Waste Management and Disposal
  • Pollution
  • Health, Toxicology and Mutagenesis

Fingerprint Dive into the research topics of 'Kinetics and mechanism of reductive dehalogenation of carbon tetrachloride using zero-valence metals'. Together they form a unique fingerprint.

  • Cite this