Laboratory detection and millimeter spectrum of the MgCCH radical

M. A. Anderson, Lucy M Ziurys

Research output: Contribution to journalArticle

37 Citations (Scopus)

Abstract

The pure rotational spectrum of the magnesium monoacetylide radical, MgCCH, has been recorded in the laboratory using millimeter/sub-mm direct absorption spectroscopy. These measurements constitute the first time this molecule has been observed in the laboratory by any spectroscopic method. Seventeen rotational transitions were observed in the frequency range 210-370 GHz for MgCCH, which appears to be a linear molecule with a 2Σ ground electronic state. Rotational and fine structure constants were determined for this radical from a nonlinear least squares fit to the data. The rotational rest frequencies measured here will enable astronomical observations to be carried out for MgCCH towards IRC +10216, where the magnesium compounds MgCN and MgNC, as well as many acetylide species, are present.

Original languageEnglish (US)
JournalAstrophysical Journal
Volume439
Issue number1 PART 2
StatePublished - Jan 20 1995
Externally publishedYes

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magnesium
magnesium compounds
rotational spectra
atomic absorption spectroscopy
molecules
absorption spectroscopy
frequency ranges
fine structure
electronics
detection
laboratory
method

Keywords

  • ISM: molecules
  • Line: identification
  • Molecular data

ASJC Scopus subject areas

  • Space and Planetary Science

Cite this

Laboratory detection and millimeter spectrum of the MgCCH radical. / Anderson, M. A.; Ziurys, Lucy M.

In: Astrophysical Journal, Vol. 439, No. 1 PART 2, 20.01.1995.

Research output: Contribution to journalArticle

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AB - The pure rotational spectrum of the magnesium monoacetylide radical, MgCCH, has been recorded in the laboratory using millimeter/sub-mm direct absorption spectroscopy. These measurements constitute the first time this molecule has been observed in the laboratory by any spectroscopic method. Seventeen rotational transitions were observed in the frequency range 210-370 GHz for MgCCH, which appears to be a linear molecule with a 2Σ ground electronic state. Rotational and fine structure constants were determined for this radical from a nonlinear least squares fit to the data. The rotational rest frequencies measured here will enable astronomical observations to be carried out for MgCCH towards IRC +10216, where the magnesium compounds MgCN and MgNC, as well as many acetylide species, are present.

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