Lanthanide hydroxide cluster complexes via ligand-controlled hydrolysis of the lanthanide ions

Zhonghao Zhang, Yanan Zhang, Zhiping Zheng

Research output: Chapter in Book/Report/Conference proceedingChapter

3 Citations (Scopus)

Abstract

We survey in this chapter the lanthanide hydroxide cluster complexes since the publication of the comprehensive review on the same subject (Handbook of physics and chemistry of rare earths 40:109-240, 2010). Specifically, polynuclear complexes with carboxylate, diketonate, phosphate, sulfonate, and polyoxometalate (POM) ligands featuring polyhedral cluster-type lanthanidehydroxo (Ln-OH) core motifs are summarized. The synthetic procedures leading to the production of the cluster species and the unique cluster core motifs are the focus of the discussion. Within each ligand family, we organize the cluster complexes according to their nuclearity with the intention to demonstrate the formal assembly of higher-nuclearity complexes using smaller and recognizable motifs as secondary building units. It is clear that a number of such motifs are prevalent and are shared by cluster complexes with ligands that are structurally and functionally distinct. With the work reviewed previously and the rapidly increasing number of polynuclear lanthanide hydroxide complexes, we hope to validate that once a synthetic serendipity, the chemistry of lanthanide hydroxide complexes is now a legitimate new paradigm of lanthanide coordination chemistry that is of fundamental interest and potential useful applications.

Original languageEnglish (US)
Title of host publicationStructure and Bonding
PublisherSpringer Verlag
Pages1-50
Number of pages50
Volume173
DOIs
StatePublished - Jan 1 2017

Publication series

NameStructure and Bonding
Volume173
ISSN (Print)00815993
ISSN (Electronic)16168550

Fingerprint

Lanthanoid Series Elements
hydroxides
hydrolysis
Hydrolysis
Ions
Ligands
ligands
ions
chemistry
Rare earths
handbooks
Physics
Phosphates
sulfonates
carboxylates
hydroxide ion
phosphates
rare earth elements
assembly
physics

Keywords

  • Cluster
  • Hydrolysis
  • Hydroxide
  • Ligand
  • Nuclearity

ASJC Scopus subject areas

  • Spectroscopy
  • Physical and Theoretical Chemistry
  • Inorganic Chemistry

Cite this

Zhang, Z., Zhang, Y., & Zheng, Z. (2017). Lanthanide hydroxide cluster complexes via ligand-controlled hydrolysis of the lanthanide ions. In Structure and Bonding (Vol. 173, pp. 1-50). (Structure and Bonding; Vol. 173). Springer Verlag. https://doi.org/10.1007/430_2016_12

Lanthanide hydroxide cluster complexes via ligand-controlled hydrolysis of the lanthanide ions. / Zhang, Zhonghao; Zhang, Yanan; Zheng, Zhiping.

Structure and Bonding. Vol. 173 Springer Verlag, 2017. p. 1-50 (Structure and Bonding; Vol. 173).

Research output: Chapter in Book/Report/Conference proceedingChapter

Zhang, Z, Zhang, Y & Zheng, Z 2017, Lanthanide hydroxide cluster complexes via ligand-controlled hydrolysis of the lanthanide ions. in Structure and Bonding. vol. 173, Structure and Bonding, vol. 173, Springer Verlag, pp. 1-50. https://doi.org/10.1007/430_2016_12
Zhang Z, Zhang Y, Zheng Z. Lanthanide hydroxide cluster complexes via ligand-controlled hydrolysis of the lanthanide ions. In Structure and Bonding. Vol. 173. Springer Verlag. 2017. p. 1-50. (Structure and Bonding). https://doi.org/10.1007/430_2016_12
Zhang, Zhonghao ; Zhang, Yanan ; Zheng, Zhiping. / Lanthanide hydroxide cluster complexes via ligand-controlled hydrolysis of the lanthanide ions. Structure and Bonding. Vol. 173 Springer Verlag, 2017. pp. 1-50 (Structure and Bonding).
@inbook{b5c8785048da454eb57c81ec73c981ce,
title = "Lanthanide hydroxide cluster complexes via ligand-controlled hydrolysis of the lanthanide ions",
abstract = "We survey in this chapter the lanthanide hydroxide cluster complexes since the publication of the comprehensive review on the same subject (Handbook of physics and chemistry of rare earths 40:109-240, 2010). Specifically, polynuclear complexes with carboxylate, diketonate, phosphate, sulfonate, and polyoxometalate (POM) ligands featuring polyhedral cluster-type lanthanidehydroxo (Ln-OH) core motifs are summarized. The synthetic procedures leading to the production of the cluster species and the unique cluster core motifs are the focus of the discussion. Within each ligand family, we organize the cluster complexes according to their nuclearity with the intention to demonstrate the formal assembly of higher-nuclearity complexes using smaller and recognizable motifs as secondary building units. It is clear that a number of such motifs are prevalent and are shared by cluster complexes with ligands that are structurally and functionally distinct. With the work reviewed previously and the rapidly increasing number of polynuclear lanthanide hydroxide complexes, we hope to validate that once a synthetic serendipity, the chemistry of lanthanide hydroxide complexes is now a legitimate new paradigm of lanthanide coordination chemistry that is of fundamental interest and potential useful applications.",
keywords = "Cluster, Hydrolysis, Hydroxide, Ligand, Nuclearity",
author = "Zhonghao Zhang and Yanan Zhang and Zhiping Zheng",
year = "2017",
month = "1",
day = "1",
doi = "10.1007/430_2016_12",
language = "English (US)",
volume = "173",
series = "Structure and Bonding",
publisher = "Springer Verlag",
pages = "1--50",
booktitle = "Structure and Bonding",
address = "Germany",

}

TY - CHAP

T1 - Lanthanide hydroxide cluster complexes via ligand-controlled hydrolysis of the lanthanide ions

AU - Zhang, Zhonghao

AU - Zhang, Yanan

AU - Zheng, Zhiping

PY - 2017/1/1

Y1 - 2017/1/1

N2 - We survey in this chapter the lanthanide hydroxide cluster complexes since the publication of the comprehensive review on the same subject (Handbook of physics and chemistry of rare earths 40:109-240, 2010). Specifically, polynuclear complexes with carboxylate, diketonate, phosphate, sulfonate, and polyoxometalate (POM) ligands featuring polyhedral cluster-type lanthanidehydroxo (Ln-OH) core motifs are summarized. The synthetic procedures leading to the production of the cluster species and the unique cluster core motifs are the focus of the discussion. Within each ligand family, we organize the cluster complexes according to their nuclearity with the intention to demonstrate the formal assembly of higher-nuclearity complexes using smaller and recognizable motifs as secondary building units. It is clear that a number of such motifs are prevalent and are shared by cluster complexes with ligands that are structurally and functionally distinct. With the work reviewed previously and the rapidly increasing number of polynuclear lanthanide hydroxide complexes, we hope to validate that once a synthetic serendipity, the chemistry of lanthanide hydroxide complexes is now a legitimate new paradigm of lanthanide coordination chemistry that is of fundamental interest and potential useful applications.

AB - We survey in this chapter the lanthanide hydroxide cluster complexes since the publication of the comprehensive review on the same subject (Handbook of physics and chemistry of rare earths 40:109-240, 2010). Specifically, polynuclear complexes with carboxylate, diketonate, phosphate, sulfonate, and polyoxometalate (POM) ligands featuring polyhedral cluster-type lanthanidehydroxo (Ln-OH) core motifs are summarized. The synthetic procedures leading to the production of the cluster species and the unique cluster core motifs are the focus of the discussion. Within each ligand family, we organize the cluster complexes according to their nuclearity with the intention to demonstrate the formal assembly of higher-nuclearity complexes using smaller and recognizable motifs as secondary building units. It is clear that a number of such motifs are prevalent and are shared by cluster complexes with ligands that are structurally and functionally distinct. With the work reviewed previously and the rapidly increasing number of polynuclear lanthanide hydroxide complexes, we hope to validate that once a synthetic serendipity, the chemistry of lanthanide hydroxide complexes is now a legitimate new paradigm of lanthanide coordination chemistry that is of fundamental interest and potential useful applications.

KW - Cluster

KW - Hydrolysis

KW - Hydroxide

KW - Ligand

KW - Nuclearity

UR - http://www.scopus.com/inward/record.url?scp=84992467134&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84992467134&partnerID=8YFLogxK

U2 - 10.1007/430_2016_12

DO - 10.1007/430_2016_12

M3 - Chapter

AN - SCOPUS:84992467134

VL - 173

T3 - Structure and Bonding

SP - 1

EP - 50

BT - Structure and Bonding

PB - Springer Verlag

ER -