Lifetimes of rovibrational levels of HD +

Nikita Kirnosov, Keeper L. Sharkey, Ludwik Adamowicz

Research output: Contribution to journalArticle

3 Scopus citations

Abstract

A method for calculating the oscillator strengths for rovibrational transitions of a diatomic system within an approach that is not based on the Born-Oppenheimer (BO) approximation is presented. The non-BO wave functions representing the bound states of the system are expanded in terms of explicitly correlated Gaussian functions. The method is applied to calculate oscillator strengths for the HD+ ion for transitions between rotationless vibrational states and vibrational states which are rotationally singly excited. The effect of the asymmetry of the HD+ charge distribution on the oscillator strengths and on the lifetimes of the states is elucidated.

Original languageEnglish (US)
Article number012513
JournalPhysical Review A - Atomic, Molecular, and Optical Physics
Volume89
Issue number1
DOIs
StatePublished - Jan 27 2014

ASJC Scopus subject areas

  • Atomic and Molecular Physics, and Optics

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