MAGNETIC SUSCEPTIBILITY ANISOTROPY, MOLECULAR g VALUES, AND OTHER MOLECULAR PROPERTIES OF CYCLOPROPANE AS DETERMINED FROM ROTATIONAL ZEEMAN STUDIES OF THE CYCLOPROPANE-H**3**5Cl AND CYCLOPROPANE-HC**1**5N COMPLEXES.

P. D. Aldrich, Stephen G Kukolich, E. J. Campbell, W. G. Read

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21 Citations (Scopus)

Abstract

A pulsed, Fourier-transform microwave spectrometer has been used to observe the rotational Zeeman effect with the cyclopropane-HCl and cyclopropane-HCN complexes. The molecular g values and magnetic susceptibility anisotropies have been determined for the cyclopropane-HCl complex and have been used to obtain the molecular quadrupole moment, magnetic susceptibility tensor elements as well as the paramagnetic and diamagnetic contributions, and the second moment of the electronic charge distribution. Certain Zeeman parameters along with zero-field rotational constants have been obtained for cyclopropane-HC**1**5N. The Zeeman constants for both complexes have then been used to extract various magnetic properties of cyclopropane.

Original languageEnglish (US)
Pages (from-to)5569-5576
Number of pages8
JournalJournal of the American Chemical Society
Volume105
Issue number17
StatePublished - Jan 1 1983
Externally publishedYes

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Anisotropy
Magnetic susceptibility
Microwave spectrometers
Charge distribution
Tensors
Magnetic properties
Fourier transforms
Fourier Analysis
Microwaves
cyclopropane

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

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title = "MAGNETIC SUSCEPTIBILITY ANISOTROPY, MOLECULAR g VALUES, AND OTHER MOLECULAR PROPERTIES OF CYCLOPROPANE AS DETERMINED FROM ROTATIONAL ZEEMAN STUDIES OF THE CYCLOPROPANE-H**3**5Cl AND CYCLOPROPANE-HC**1**5N COMPLEXES.",
abstract = "A pulsed, Fourier-transform microwave spectrometer has been used to observe the rotational Zeeman effect with the cyclopropane-HCl and cyclopropane-HCN complexes. The molecular g values and magnetic susceptibility anisotropies have been determined for the cyclopropane-HCl complex and have been used to obtain the molecular quadrupole moment, magnetic susceptibility tensor elements as well as the paramagnetic and diamagnetic contributions, and the second moment of the electronic charge distribution. Certain Zeeman parameters along with zero-field rotational constants have been obtained for cyclopropane-HC**1**5N. The Zeeman constants for both complexes have then been used to extract various magnetic properties of cyclopropane.",
author = "Aldrich, {P. D.} and Kukolich, {Stephen G} and Campbell, {E. J.} and Read, {W. G.}",
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T1 - MAGNETIC SUSCEPTIBILITY ANISOTROPY, MOLECULAR g VALUES, AND OTHER MOLECULAR PROPERTIES OF CYCLOPROPANE AS DETERMINED FROM ROTATIONAL ZEEMAN STUDIES OF THE CYCLOPROPANE-H**3**5Cl AND CYCLOPROPANE-HC**1**5N COMPLEXES.

AU - Aldrich, P. D.

AU - Kukolich, Stephen G

AU - Campbell, E. J.

AU - Read, W. G.

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Y1 - 1983/1/1

N2 - A pulsed, Fourier-transform microwave spectrometer has been used to observe the rotational Zeeman effect with the cyclopropane-HCl and cyclopropane-HCN complexes. The molecular g values and magnetic susceptibility anisotropies have been determined for the cyclopropane-HCl complex and have been used to obtain the molecular quadrupole moment, magnetic susceptibility tensor elements as well as the paramagnetic and diamagnetic contributions, and the second moment of the electronic charge distribution. Certain Zeeman parameters along with zero-field rotational constants have been obtained for cyclopropane-HC**1**5N. The Zeeman constants for both complexes have then been used to extract various magnetic properties of cyclopropane.

AB - A pulsed, Fourier-transform microwave spectrometer has been used to observe the rotational Zeeman effect with the cyclopropane-HCl and cyclopropane-HCN complexes. The molecular g values and magnetic susceptibility anisotropies have been determined for the cyclopropane-HCl complex and have been used to obtain the molecular quadrupole moment, magnetic susceptibility tensor elements as well as the paramagnetic and diamagnetic contributions, and the second moment of the electronic charge distribution. Certain Zeeman parameters along with zero-field rotational constants have been obtained for cyclopropane-HC**1**5N. The Zeeman constants for both complexes have then been used to extract various magnetic properties of cyclopropane.

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