Maleimide functionalized siloxane resins

R. M. Shaltout, Douglas A Loy, D. R. Wheeler

Research output: Chapter in Book/Report/Conference proceedingConference contribution

5 Citations (Scopus)

Abstract

In-situ filling through hydrolysis and condensation of silicon alkoxides dissolved into polymers has been utilized to generate nanocomposites in which the filler phase can be intimately associated with the polymer on relatively small length scales. One problem of the method has been achieving useful fill volumes without bulk phase separation of the growing inorganic component from the polymer. In this paper, we describe the preparation of a new class of nanocomposite materials in which the inorganic filler phase is pre-assembled before copolymerization with an organic monomer. Maleimide monomers, prepared from alkoxysilylpropyl amines and maleic anhydride, were protected against side reactions by forming the oxonorbornene Diels-Alder adduct with furan. The monomers were then reacted under sol-gel conditions to form oligomers or polymers making up the filler phase. The material was activated by thermal deprotection of the maleimide and reacted with organic monomers or polymers to form the filled nanocomposite.

Original languageEnglish (US)
Title of host publicationMaterials Research Society Symposium - Proceedings
PublisherMaterials Research Society
Pages15-20
Number of pages6
Volume576
StatePublished - 1999
Externally publishedYes
EventProceedings of the 1999 MRS Spring Meeting - Symposium DD, 'Organic/Inorganic Hybrid Materials' - San Francisco, CA, USA
Duration: Apr 5 1999Apr 9 1999

Other

OtherProceedings of the 1999 MRS Spring Meeting - Symposium DD, 'Organic/Inorganic Hybrid Materials'
CitySan Francisco, CA, USA
Period4/5/994/9/99

Fingerprint

Siloxanes
Polymers
Resins
Monomers
Fillers
Nanocomposites
Maleic Anhydrides
Maleic anhydride
Silicon
Oligomers
Phase separation
Copolymerization
Amines
Sol-gels
Condensation
Hydrolysis
maleimide

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials

Cite this

Shaltout, R. M., Loy, D. A., & Wheeler, D. R. (1999). Maleimide functionalized siloxane resins. In Materials Research Society Symposium - Proceedings (Vol. 576, pp. 15-20). Materials Research Society.

Maleimide functionalized siloxane resins. / Shaltout, R. M.; Loy, Douglas A; Wheeler, D. R.

Materials Research Society Symposium - Proceedings. Vol. 576 Materials Research Society, 1999. p. 15-20.

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Shaltout, RM, Loy, DA & Wheeler, DR 1999, Maleimide functionalized siloxane resins. in Materials Research Society Symposium - Proceedings. vol. 576, Materials Research Society, pp. 15-20, Proceedings of the 1999 MRS Spring Meeting - Symposium DD, 'Organic/Inorganic Hybrid Materials', San Francisco, CA, USA, 4/5/99.
Shaltout RM, Loy DA, Wheeler DR. Maleimide functionalized siloxane resins. In Materials Research Society Symposium - Proceedings. Vol. 576. Materials Research Society. 1999. p. 15-20
Shaltout, R. M. ; Loy, Douglas A ; Wheeler, D. R. / Maleimide functionalized siloxane resins. Materials Research Society Symposium - Proceedings. Vol. 576 Materials Research Society, 1999. pp. 15-20
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