Measurement of Cl and N quadrupole coupling in ClCN

C. D. Cogley, H. A. Fry, Stephen G Kukolich

Research output: Contribution to journalArticle

8 Citations (Scopus)

Abstract

J = 1 ← 0 and J = 2 ← 1 transitions in 35ClCN and 37ClCN were measured using a C-band waveguide spectrometer and phase-locked sources. Parameters obtained from the data are: B(35ClCN) = 5 970.820 ± 0.010 MHz, B(37ClCN) = 5 847.246 ± 0.008 MHz, eqQ(35Cl) = -83.26 ± 0.04 MHz, eqQ(37Cl) = -65.61 ± 0.04 MHz and eqQ(14N) = -3.60 ± 0.08 MHz.

Original languageEnglish (US)
Pages (from-to)447-453
Number of pages7
JournalJournal of Molecular Spectroscopy
Volume75
Issue number3
DOIs
StatePublished - Jun 1 1979

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C band
Spectrometers
Waveguides
quadrupoles
spectrometers
waveguides

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Spectroscopy
  • Atomic and Molecular Physics, and Optics

Cite this

Measurement of Cl and N quadrupole coupling in ClCN. / Cogley, C. D.; Fry, H. A.; Kukolich, Stephen G.

In: Journal of Molecular Spectroscopy, Vol. 75, No. 3, 01.06.1979, p. 447-453.

Research output: Contribution to journalArticle

Cogley, C. D. ; Fry, H. A. ; Kukolich, Stephen G. / Measurement of Cl and N quadrupole coupling in ClCN. In: Journal of Molecular Spectroscopy. 1979 ; Vol. 75, No. 3. pp. 447-453.
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AB - J = 1 ← 0 and J = 2 ← 1 transitions in 35ClCN and 37ClCN were measured using a C-band waveguide spectrometer and phase-locked sources. Parameters obtained from the data are: B(35ClCN) = 5 970.820 ± 0.010 MHz, B(37ClCN) = 5 847.246 ± 0.008 MHz, eqQ(35Cl) = -83.26 ± 0.04 MHz, eqQ(37Cl) = -65.61 ± 0.04 MHz and eqQ(14N) = -3.60 ± 0.08 MHz.

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