Measurement of the dipole moment of CF3CN

P. B. Foreman, K. R. Chien, J. R. Williams, Stephen G Kukolich

Research output: Contribution to journalArticle

6 Citations (Scopus)

Abstract

The Stark effect was observed for K = 0 and K = 1, J = 1 → 2 transitions in CF3CN. Measurements were made in a Stark modulated microwave spectrometer. The dipole moment obtained was μ = 1.262 ± 0.010 D. An analysis of the effects of electric field inhomogeneities on the observed Stark shifts for K = 0 and K = 1 states is included. Appropriate corrections are given for measuring linear Stark effects in a standard waveguide cell calibrated using a molecule with second-order Stark effect.

Original languageEnglish (US)
Pages (from-to)251-255
Number of pages5
JournalJournal of Molecular Spectroscopy
Volume52
Issue number2
DOIs
StatePublished - 1974
Externally publishedYes

Fingerprint

Stark effect
Dipole moment
dipole moments
Microwave spectrometers
microwave spectrometers
inhomogeneity
Waveguides
Electric fields
waveguides
Molecules
electric fields
shift
cells
molecules

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Spectroscopy
  • Atomic and Molecular Physics, and Optics

Cite this

Measurement of the dipole moment of CF3CN. / Foreman, P. B.; Chien, K. R.; Williams, J. R.; Kukolich, Stephen G.

In: Journal of Molecular Spectroscopy, Vol. 52, No. 2, 1974, p. 251-255.

Research output: Contribution to journalArticle

Foreman, P. B. ; Chien, K. R. ; Williams, J. R. ; Kukolich, Stephen G. / Measurement of the dipole moment of CF3CN. In: Journal of Molecular Spectroscopy. 1974 ; Vol. 52, No. 2. pp. 251-255.
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