Measurements of microwave rotational transitions for cyclopentadienyltungsten dicarbonyl nitrosyl

S. G. Kukolich, R. T. McKay, L. D. Flores, G. E. Morris

Research output: Contribution to journalArticlepeer-review

2 Scopus citations

Abstract

The microwave spectrum of (η5-C5H5)W(CO)2NO was observed using a Flygare-Balle type pulsed beam spectrometer. Fourteen a-dipole transitions in the 5-10 GHz range were measured. Rotational constants obtained are A = 952.(1) MHz, B = 708.316(2) MHz, and C = 701.857(2) MHz. Structural parameters obtained from the data analysis are r(C5H5-W) = 2.06(3) Å, ∠C5H5-W-N = 122.7(10)°, and ∠C5H5-W-CO = 123.2(10)°. The difference between the nitrosyl and carbonyl angles with respect to the C5H5 symmetry axis is much smaller for this complex than for the C5H5Cr(CO)2NO complex.

Original languageEnglish (US)
Pages (from-to)11820-11822
Number of pages3
JournalJournal of physical chemistry
Volume99
Issue number31
DOIs
StatePublished - Jan 1 1995

ASJC Scopus subject areas

  • Engineering(all)
  • Physical and Theoretical Chemistry

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