Microwave measurements of bromine quadrupole coupling constants and the molecular structure of XeHBr

S. G. Kukolich; E. J. Campbell

doi:10.1016/0009-2614(83)87213-3

Microwave measurements of bromine quadrupole coupling constants and the molecular structure of XeHBr

S. G. Kukolich, E. J. Campbell

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18 Scopus citations

Abstract

Microwave rotational spectra for various isotopic forms of the XeHBr complex were obtained using a pulsed-nozzle, Fourier transform spectrometer. The molecular constants (eQq), B₀ and D_j were obtained from J = 6 → 7, 7 → 8 and 8 → 9 transitions. The xenon-bromine separation distance is r_Xe-Br = 4.419 Å. From D_j a stretching force constant k_s = 0.018 mdyne/Å and well depth ε{lunate} = 244 cm^-1 were obtained.

Original language	English (US)
Pages (from-to)	73-76
Number of pages	4
Journal	Chemical Physics Letters
Volume	94
Issue number	1
DOIs	https://doi.org/10.1016/0009-2614(83)87213-3
State	Published - Jan 7 1983
Externally published	Yes

ASJC Scopus subject areas

Physics and Astronomy(all)
Physical and Theoretical Chemistry

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10.1016/0009-2614(83)87213-3

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title = "Microwave measurements of bromine quadrupole coupling constants and the molecular structure of XeHBr",

abstract = "Microwave rotational spectra for various isotopic forms of the XeHBr complex were obtained using a pulsed-nozzle, Fourier transform spectrometer. The molecular constants (eQq), B0 and Dj were obtained from J = 6 → 7, 7 → 8 and 8 → 9 transitions. The xenon-bromine separation distance is rXe-Br = 4.419 {\AA}. From Dj a stretching force constant ks = 0.018 mdyne/{\AA} and well depth ε{lunate} = 244 cm-1 were obtained.",

author = "Kukolich, {S. G.} and Campbell, {E. J.}",

year = "1983",

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T1 - Microwave measurements of bromine quadrupole coupling constants and the molecular structure of XeHBr

AU - Kukolich, S. G.

AU - Campbell, E. J.

PY - 1983/1/7

Y1 - 1983/1/7

N2 - Microwave rotational spectra for various isotopic forms of the XeHBr complex were obtained using a pulsed-nozzle, Fourier transform spectrometer. The molecular constants (eQq), B0 and Dj were obtained from J = 6 → 7, 7 → 8 and 8 → 9 transitions. The xenon-bromine separation distance is rXe-Br = 4.419 Å. From Dj a stretching force constant ks = 0.018 mdyne/Å and well depth ε{lunate} = 244 cm-1 were obtained.

AB - Microwave rotational spectra for various isotopic forms of the XeHBr complex were obtained using a pulsed-nozzle, Fourier transform spectrometer. The molecular constants (eQq), B0 and Dj were obtained from J = 6 → 7, 7 → 8 and 8 → 9 transitions. The xenon-bromine separation distance is rXe-Br = 4.419 Å. From Dj a stretching force constant ks = 0.018 mdyne/Å and well depth ε{lunate} = 244 cm-1 were obtained.

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JF - Chemical Physics Letters

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Microwave measurements of bromine quadrupole coupling constants and the molecular structure of XeHBr

Abstract

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