Microwave measurements of bromine quadrupole coupling constants and the molecular structure of XeHBr

S. G. Kukolich, E. J. Campbell

Research output: Contribution to journalArticlepeer-review

18 Scopus citations

Abstract

Microwave rotational spectra for various isotopic forms of the XeHBr complex were obtained using a pulsed-nozzle, Fourier transform spectrometer. The molecular constants (eQq), B0 and Dj were obtained from J = 6 → 7, 7 → 8 and 8 → 9 transitions. The xenon-bromine separation distance is rXe-Br = 4.419 Å. From Dj a stretching force constant ks = 0.018 mdyne/Å and well depth ε{lunate} = 244 cm-1 were obtained.

Original languageEnglish (US)
Pages (from-to)73-76
Number of pages4
JournalChemical Physics Letters
Volume94
Issue number1
DOIs
StatePublished - Jan 7 1983
Externally publishedYes

ASJC Scopus subject areas

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

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