Microwave measurements of cyclopropanecarboxylic acid and -OD isotopologue

Aaron M. Pejlovas, Kexin Li, Stephen G. Kukolich

Research output: Contribution to journalArticlepeer-review

2 Scopus citations

Abstract

The microwave spectrum of cyclopropanecarboxylic acid has been measured in the 5-15 GHz region using a Flygare-Balle type, pulsed-beam Fourier-transform microwave spectrometer. These lower-frequency measurements are at a much higher resolution then the previous waveguide studies. The experimental rotational constants obtained in this study were A = 7625.0432(17) MHz, B = 2724.7672(8) MHz, and C = 2382.0755(5) MHz. The centrifugal distortion constants determined were ΔJ = 0.4010(25) kHz, ΔJK = 3.04(17) kHz, ΔJ = 0.0434(72) kHz, and ΔK = -11.32(24) kHz.

Original languageEnglish (US)
Pages (from-to)1-3
Number of pages3
JournalJournal of Molecular Spectroscopy
Volume313
DOIs
StatePublished - Jul 1 2015

Keywords

  • Calculated structure
  • Carboxylic acid
  • Microwave spectroscopy

ASJC Scopus subject areas

  • Atomic and Molecular Physics, and Optics
  • Spectroscopy
  • Physical and Theoretical Chemistry

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