Microwave spectra and the metal-hydrogen bond lengths for the C 5H 5Mo(CO) 3H and C 5H 5W(CO) 3H complexes

Chakree Tanjaroon, Kristen S. Keck, Matthew M. Sebonia, Chandana Karunatilaka, Stephen G Kukolich

Research output: Contribution to journalArticle

11 Citations (Scopus)

Abstract

The microwave spectra and the metal-hydrogen bond lengths for the C 5H 5Mo(CO) 3H and C 5H 5W(CO) 3H complexes were analyzed. The sample was heated to produce vapor pressure before pulsing of the sample into the microwave cavity. Measurement of rotational frequencies in the range of 4-12 GHz were performed using a pulsed beam fourier transform microwave spectrometer. Result shows that the Mo-H value is in good agreement with the x ray and neutron diffraction studies of similar complexes.

Original languageEnglish (US)
Pages (from-to)1449-1453
Number of pages5
JournalThe Journal of Chemical Physics
Volume121
Issue number3
DOIs
StatePublished - Jul 15 2004

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microwave spectra
Bond length
Carbon Monoxide
Hydrogen bonds
Microwave spectrometers
Metals
Microwaves
hydrogen bonds
microwave spectrometers
Neutron diffraction
Vapor pressure
metals
vapor pressure
neutron diffraction
Fourier transforms
x ray diffraction
microwaves
X rays
cavities

ASJC Scopus subject areas

  • Atomic and Molecular Physics, and Optics

Cite this

Microwave spectra and the metal-hydrogen bond lengths for the C 5H 5Mo(CO) 3H and C 5H 5W(CO) 3H complexes. / Tanjaroon, Chakree; Keck, Kristen S.; Sebonia, Matthew M.; Karunatilaka, Chandana; Kukolich, Stephen G.

In: The Journal of Chemical Physics, Vol. 121, No. 3, 15.07.2004, p. 1449-1453.

Research output: Contribution to journalArticle

Tanjaroon, Chakree ; Keck, Kristen S. ; Sebonia, Matthew M. ; Karunatilaka, Chandana ; Kukolich, Stephen G. / Microwave spectra and the metal-hydrogen bond lengths for the C 5H 5Mo(CO) 3H and C 5H 5W(CO) 3H complexes. In: The Journal of Chemical Physics. 2004 ; Vol. 121, No. 3. pp. 1449-1453.
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