Microwave Spectrum and Molecular Structure for Manganese Pentacarbonyl Hydride

Stephen G. Kukolich, Shane M. Sickafoose

Research output: Contribution to journalArticle

14 Scopus citations

Abstract

Microwave rotational transitions for HMn(CO)5 with 13C isotopic substitution in the axial and in one equatorial site were measured using a Flygare-Balle-type pulsed-beam spectrometer. Rotational constants obtained are A = B = 903.433(1) MHz for the axial 13CO isotopomer and A = 902.278(3) MHz and B = 907.761(3) MHz for the isotopomer with one equatorial 13C substitution. The new data are combined with previous data on HMn(CO)5 and DMn(CO)5 to obtain structural parameters for this complex. The Mn-H bond length obtained is r(Mn-H) = 1.65(2) Å and ∠Cax-Mn-Ceq = 97.0(5)°.

Original languageEnglish (US)
Pages (from-to)1217-1219
Number of pages3
JournalInorganic Chemistry
Volume33
Issue number6
DOIs
StatePublished - Mar 1 1994

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry

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