Millimeter-wave rotational spectroscopy of MgOD and CaOD (X 2Σ+)

B. P. Nuccio, A. J. Apponi, L. M. Ziurys

Research output: Contribution to journalArticlepeer-review

14 Scopus citations

Abstract

Pure rotational spectra of CaOD and MgOD have been recorded in the range 200-390 GHz using millimeter/sub-mm direct absorption spectroscopy. Transitions arising from the (000), (010), (020), and (100) modes have been measured for the 2Σ+ ground electronic states of these free radicals. The data were analyzed successfully using a linear 2Σ+ model for CaOD; for MgOD, only the (000) and (010) states could be fit with this Hamiltonian. Moreover, the (010) data required the addition of a substantial pΠ term to account for contamination of excited 2Π electronic states. For both species, the α2 vibration-rotation term was found to be negative, in contrast to MgOH and CaOH, suggesting a less anharmonic contribution to the bending potential in CaOD and MgOD. These measurements also indicate a shorter O-H bond in MgOH than the other alkaline earth hydroxide radicals, which likely results because this species is quasilinear.

Original languageEnglish (US)
Pages (from-to)9193-9199
Number of pages7
JournalThe Journal of Chemical Physics
Volume103
Issue number21
DOIs
StatePublished - Jan 1 1995
Externally publishedYes

ASJC Scopus subject areas

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

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