Model pyroxenes II

Structural variation as a function of tetrahedral rotation

Richard M. Thompson, Robert T Downs

Research output: Contribution to journalArticle

39 Citations (Scopus)

Abstract

Model pyroxenes with regular tetrahedral and MI octahedral coordination polyhedra have been derived. The M2 polyhedron is not constrained to be regular. These models are parameterized in terms of the O3-O3-O3 angle, θ, and the model O atom radius, r. Crystallographic parameters such as interatomic distances, unit cell volume, and packing distortion are determined as a function of the O3-O3-O3 angle. Results are compared with observed pyroxenes, providing insight into which interatomic interactions are important in determining pyroxene topology and behavior. Temperature is shown to favor polyhedral regularity in orthopyroxene and protopyroxene. Compression and expansion strain ellipsoids for observed and model pyroxenes are compared, demonstrating that a combination of tetrahedral rotation and isotropic compression approximately reproduces the compression ellipsoids of pyroxenes. but not the expansion ellipsoids.

Original languageEnglish (US)
Pages (from-to)614-628
Number of pages15
JournalAmerican Mineralogist
Volume89
Issue number4
StatePublished - Apr 2004

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pyroxenes
ellipsoids
compression
polyhedrons
expansion
orthopyroxene
regularity
pyroxene
topology
Topology
Atoms
radii
cells
atoms
temperature
interactions
Temperature

ASJC Scopus subject areas

  • Geochemistry and Petrology
  • Geophysics

Cite this

Model pyroxenes II : Structural variation as a function of tetrahedral rotation. / Thompson, Richard M.; Downs, Robert T.

In: American Mineralogist, Vol. 89, No. 4, 04.2004, p. 614-628.

Research output: Contribution to journalArticle

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