Modification of the surface properties of indium tin oxide with benzylphosphonic acids: A joint experimental and theoretical study

Peter J. Hotchkiss, Hong Li, Pavel B. Paramonov, Sergio A. Paniagua, Simon C. Jones, Neal R Armstrong, Jean Luc Brédas, Seth R. Marder

Research output: Contribution to journalArticle

113 Citations (Scopus)

Abstract

(Figure Presented) Benzylphosphonic acids with various fluorine substitutions are designed and synthesized. They are used to modify ITO such that the work function can be tuned over a range of 1.2 eV while keeping the surface energy relatively constant. The experimentally measured work function changes are also compared to and agree well with those estimated from DFT calculations.

Original languageEnglish (US)
Pages (from-to)4496-4501
Number of pages6
JournalAdvanced Materials
Volume21
Issue number44
DOIs
StatePublished - Nov 26 2009

Fingerprint

Tin oxides
Indium
Surface properties
Acids
Fluorine
Interfacial energy
Discrete Fourier transforms
Substitution reactions
indium tin oxide
benzylphosphonic acid

ASJC Scopus subject areas

  • Materials Science(all)
  • Mechanics of Materials
  • Mechanical Engineering

Cite this

Modification of the surface properties of indium tin oxide with benzylphosphonic acids : A joint experimental and theoretical study. / Hotchkiss, Peter J.; Li, Hong; Paramonov, Pavel B.; Paniagua, Sergio A.; Jones, Simon C.; Armstrong, Neal R; Brédas, Jean Luc; Marder, Seth R.

In: Advanced Materials, Vol. 21, No. 44, 26.11.2009, p. 4496-4501.

Research output: Contribution to journalArticle

Hotchkiss, Peter J. ; Li, Hong ; Paramonov, Pavel B. ; Paniagua, Sergio A. ; Jones, Simon C. ; Armstrong, Neal R ; Brédas, Jean Luc ; Marder, Seth R. / Modification of the surface properties of indium tin oxide with benzylphosphonic acids : A joint experimental and theoretical study. In: Advanced Materials. 2009 ; Vol. 21, No. 44. pp. 4496-4501.
@article{e7b06f3d2f1b477cb355f6d0a895d8c0,
title = "Modification of the surface properties of indium tin oxide with benzylphosphonic acids: A joint experimental and theoretical study",
abstract = "(Figure Presented) Benzylphosphonic acids with various fluorine substitutions are designed and synthesized. They are used to modify ITO such that the work function can be tuned over a range of 1.2 eV while keeping the surface energy relatively constant. The experimentally measured work function changes are also compared to and agree well with those estimated from DFT calculations.",
author = "Hotchkiss, {Peter J.} and Hong Li and Paramonov, {Pavel B.} and Paniagua, {Sergio A.} and Jones, {Simon C.} and Armstrong, {Neal R} and Br{\'e}das, {Jean Luc} and Marder, {Seth R.}",
year = "2009",
month = "11",
day = "26",
doi = "10.1002/adma.200900502",
language = "English (US)",
volume = "21",
pages = "4496--4501",
journal = "Advanced Materials",
issn = "0935-9648",
publisher = "Wiley-VCH Verlag",
number = "44",

}

TY - JOUR

T1 - Modification of the surface properties of indium tin oxide with benzylphosphonic acids

T2 - A joint experimental and theoretical study

AU - Hotchkiss, Peter J.

AU - Li, Hong

AU - Paramonov, Pavel B.

AU - Paniagua, Sergio A.

AU - Jones, Simon C.

AU - Armstrong, Neal R

AU - Brédas, Jean Luc

AU - Marder, Seth R.

PY - 2009/11/26

Y1 - 2009/11/26

N2 - (Figure Presented) Benzylphosphonic acids with various fluorine substitutions are designed and synthesized. They are used to modify ITO such that the work function can be tuned over a range of 1.2 eV while keeping the surface energy relatively constant. The experimentally measured work function changes are also compared to and agree well with those estimated from DFT calculations.

AB - (Figure Presented) Benzylphosphonic acids with various fluorine substitutions are designed and synthesized. They are used to modify ITO such that the work function can be tuned over a range of 1.2 eV while keeping the surface energy relatively constant. The experimentally measured work function changes are also compared to and agree well with those estimated from DFT calculations.

UR - http://www.scopus.com/inward/record.url?scp=72049100924&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=72049100924&partnerID=8YFLogxK

U2 - 10.1002/adma.200900502

DO - 10.1002/adma.200900502

M3 - Article

AN - SCOPUS:72049100924

VL - 21

SP - 4496

EP - 4501

JO - Advanced Materials

JF - Advanced Materials

SN - 0935-9648

IS - 44

ER -