Molecules in high spin states: The millimeter and submillimeter spectrum of the MnS radical (X 6Σ+)

J. M. Thompsen, M. A. Brewster, Lucy M Ziurys

Research output: Contribution to journalArticle

11 Citations (Scopus)

Abstract

The pure rotational spectrum of MnS (v = 0) in its X6σ+ ground state was discussed using millimeter and submillimeter direct absorption techniques. MnS was synthesized in the gas phase by the reaction of manganese vapor and CS2 in a high-temperature Borida-type oven and fourteen rotational transitions were measured for this radical. The analysis showed that MnS was more covalent than MnO but more ionic than MnH.

Original languageEnglish (US)
Pages (from-to)10212-10220
Number of pages9
JournalThe Journal of Chemical Physics
Volume116
Issue number23
DOIs
StatePublished - Jun 23 2002

Fingerprint

ovens
rotational spectra
Ovens
Manganese
Ground state
manganese
Gases
Vapors
vapors
vapor phases
Molecules
ground state
molecules
Temperature

ASJC Scopus subject areas

  • Atomic and Molecular Physics, and Optics

Cite this

Molecules in high spin states : The millimeter and submillimeter spectrum of the MnS radical (X 6Σ+). / Thompsen, J. M.; Brewster, M. A.; Ziurys, Lucy M.

In: The Journal of Chemical Physics, Vol. 116, No. 23, 23.06.2002, p. 10212-10220.

Research output: Contribution to journalArticle

@article{8d8e39962c1243878ee9a95645a5c81c,
title = "Molecules in high spin states: The millimeter and submillimeter spectrum of the MnS radical (X 6Σ+)",
abstract = "The pure rotational spectrum of MnS (v = 0) in its X6σ+ ground state was discussed using millimeter and submillimeter direct absorption techniques. MnS was synthesized in the gas phase by the reaction of manganese vapor and CS2 in a high-temperature Borida-type oven and fourteen rotational transitions were measured for this radical. The analysis showed that MnS was more covalent than MnO but more ionic than MnH.",
author = "Thompsen, {J. M.} and Brewster, {M. A.} and Ziurys, {Lucy M}",
year = "2002",
month = "6",
day = "23",
doi = "10.1063/1.1476931",
language = "English (US)",
volume = "116",
pages = "10212--10220",
journal = "Journal of Chemical Physics",
issn = "0021-9606",
publisher = "American Institute of Physics Publising LLC",
number = "23",

}

TY - JOUR

T1 - Molecules in high spin states

T2 - The millimeter and submillimeter spectrum of the MnS radical (X 6Σ+)

AU - Thompsen, J. M.

AU - Brewster, M. A.

AU - Ziurys, Lucy M

PY - 2002/6/23

Y1 - 2002/6/23

N2 - The pure rotational spectrum of MnS (v = 0) in its X6σ+ ground state was discussed using millimeter and submillimeter direct absorption techniques. MnS was synthesized in the gas phase by the reaction of manganese vapor and CS2 in a high-temperature Borida-type oven and fourteen rotational transitions were measured for this radical. The analysis showed that MnS was more covalent than MnO but more ionic than MnH.

AB - The pure rotational spectrum of MnS (v = 0) in its X6σ+ ground state was discussed using millimeter and submillimeter direct absorption techniques. MnS was synthesized in the gas phase by the reaction of manganese vapor and CS2 in a high-temperature Borida-type oven and fourteen rotational transitions were measured for this radical. The analysis showed that MnS was more covalent than MnO but more ionic than MnH.

UR - http://www.scopus.com/inward/record.url?scp=0037162249&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0037162249&partnerID=8YFLogxK

U2 - 10.1063/1.1476931

DO - 10.1063/1.1476931

M3 - Article

AN - SCOPUS:0037162249

VL - 116

SP - 10212

EP - 10220

JO - Journal of Chemical Physics

JF - Journal of Chemical Physics

SN - 0021-9606

IS - 23

ER -