Molybdate templated assembly of ln12mo4-type clusters (ln = sm, eu, gd) containing a truncated tetrahedron core

Yong Zheng, Qian Chong Zhang, La Sheng Long, Rong Bin Huang, Achim Müller, Jürgen Schnack, Lan Sun Zheng, Zhiping Zheng

Research output: Contribution to journalArticle

57 Scopus citations

Abstract

Three heterometallic cluster complexes {Ln12Mo4} featuring an Ln12 core of a distorted truncated tetrahedron were synthesized with the assistance of four MoO42− anions as ancillary ligands. Magnetic studies of the {Gd12Mo4} cluster revealed a large magnetocaloric effect due to the presence of the large number of weakly coupled Gd(iii) ions.

Original languageEnglish (US)
Pages (from-to)36-38
Number of pages3
JournalChemical Communications
Volume49
Issue number1
DOIs
StatePublished - Jan 1 2013

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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