Molybdate templated assembly of Ln12Mo4-type clusters (Ln = Sm, Eu, Gd) containing a truncated tetrahedron core

Yong Zheng, Qian Chong Zhang, La Sheng Long, Rong Bin Huang, Achim Müller, Jürgen Schnack, Lan Sun Zheng, Zhiping Zheng

Research output: Contribution to journalArticle

54 Citations (Scopus)

Abstract

Three heterometallic cluster complexes {Ln12Mo4} featuring an Ln12 core of a distorted truncated tetrahedron were synthesized with the assistance of four MoO42- anions as ancillary ligands. Magnetic studies of the {Gd12Mo4} cluster revealed a large magnetocaloric effect due to the presence of the large number of weakly coupled Gd(iii) ions.

Original languageEnglish (US)
Pages (from-to)36-38
Number of pages3
JournalChemical Communications
Volume49
Issue number1
DOIs
StatePublished - Jan 4 2013
Externally publishedYes

Fingerprint

Magnetocaloric effects
Anions
Negative ions
Ligands
Ions
molybdate

ASJC Scopus subject areas

  • Metals and Alloys
  • Materials Chemistry
  • Surfaces, Coatings and Films
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Catalysis
  • Chemistry(all)

Cite this

Molybdate templated assembly of Ln12Mo4-type clusters (Ln = Sm, Eu, Gd) containing a truncated tetrahedron core. / Zheng, Yong; Zhang, Qian Chong; Long, La Sheng; Huang, Rong Bin; Müller, Achim; Schnack, Jürgen; Zheng, Lan Sun; Zheng, Zhiping.

In: Chemical Communications, Vol. 49, No. 1, 04.01.2013, p. 36-38.

Research output: Contribution to journalArticle

Zheng, Yong ; Zhang, Qian Chong ; Long, La Sheng ; Huang, Rong Bin ; Müller, Achim ; Schnack, Jürgen ; Zheng, Lan Sun ; Zheng, Zhiping. / Molybdate templated assembly of Ln12Mo4-type clusters (Ln = Sm, Eu, Gd) containing a truncated tetrahedron core. In: Chemical Communications. 2013 ; Vol. 49, No. 1. pp. 36-38.
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AU - Müller, Achim

AU - Schnack, Jürgen

AU - Zheng, Lan Sun

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