Multinuclear NMR Studies of Electron Distributions: 14N, 13C, and 95Mo Spectra of and Thionitrosyl Complexes of Chromium, Molybdenum, and Tungsten

Martin Minelli, John L. Hubbard, Dennis L. Lichtenberger, John H. Enemar

Research output: Contribution to journalArticle

16 Scopus citations

Abstract

Previously we have shown that 14N and 95Mo NMR are useful techniques for studying piano stool nitrosyl complexes such as (η5-C5H5)Mo(CO)2NO.1 Recently a number of related nitrosyl and thionitrosyl complexes of group 6 metals have been synthesized.2,3 The availability of new thionitrosyl complexes of the Cr, Mo, W triad has permitted us to directly compare the spectroscopic properties of several pairs of metal nitrosyl/thionitrosyl species. Here we present the first nitrogen NMR data for a thionitrosyl complex, and we demonstrate the applicability of 14N NMR, particularly in combination with 95Mo NMR and 13C NMR, for providing specific experimental information on the relative electron distribution and bonding of nitrosyls and thionitrosyls with metals.

Original languageEnglish (US)
Pages (from-to)2721-2722
Number of pages2
JournalInorganic Chemistry
Volume23
Issue number17
DOIs
StatePublished - Jan 1984

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry

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