NiMoO4 selective oxidation catalysts containing excess MoO3 for the conversion of C4 hydrocarbons to maleic anhydride. III. Selective oxidation of 1,3-butadiene and furan

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Abstract

The selective oxidation of 1,3-butadiene and furan to maleic anhydride over NiMoO4 catalysts containing excess MoO3 was investigated. Activity and selectivity measurements were performed using a fixed-bed, integral reactor system. The results were compared with those obtained for 1-butene oxidation which indicated the most selective component of the catalyst for maleic anhydride formation was a MoO3 phase having a surface covering of NiMoO4; similar results were found to be applicable for 1,3-butadiene and furan oxidation. NiMoO44 was determined to be the catalyst component responsible for oxidative dehydrogenation of 1-butene; this phase also selectively blocked complete oxidation sites on MoO3, thereby changing the selectivity in favor of maleic anhydride.

Original languageEnglish (US)
Pages (from-to)147-154
Number of pages8
JournalJournal of Catalysis
Volume95
Issue number1
DOIs
StatePublished - 1985
Externally publishedYes

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Maleic Anhydrides
furans
Maleic anhydride
anhydrides
butadiene
Hydrocarbons
Butadiene
hydrocarbons
catalysts
Oxidation
oxidation
Catalysts
butenes
Butenes
selectivity
Dehydrogenation
dehydrogenation
beds
coverings
reactors

ASJC Scopus subject areas

  • Catalysis
  • Process Chemistry and Technology

Cite this

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title = "NiMoO4 selective oxidation catalysts containing excess MoO3 for the conversion of C4 hydrocarbons to maleic anhydride. III. Selective oxidation of 1,3-butadiene and furan",
abstract = "The selective oxidation of 1,3-butadiene and furan to maleic anhydride over NiMoO4 catalysts containing excess MoO3 was investigated. Activity and selectivity measurements were performed using a fixed-bed, integral reactor system. The results were compared with those obtained for 1-butene oxidation which indicated the most selective component of the catalyst for maleic anhydride formation was a MoO3 phase having a surface covering of NiMoO4; similar results were found to be applicable for 1,3-butadiene and furan oxidation. NiMoO44 was determined to be the catalyst component responsible for oxidative dehydrogenation of 1-butene; this phase also selectively blocked complete oxidation sites on MoO3, thereby changing the selectivity in favor of maleic anhydride.",
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T1 - NiMoO4 selective oxidation catalysts containing excess MoO3 for the conversion of C4 hydrocarbons to maleic anhydride. III. Selective oxidation of 1,3-butadiene and furan

AU - Ozkan, U.

AU - Schrader, Glenn L

PY - 1985

Y1 - 1985

N2 - The selective oxidation of 1,3-butadiene and furan to maleic anhydride over NiMoO4 catalysts containing excess MoO3 was investigated. Activity and selectivity measurements were performed using a fixed-bed, integral reactor system. The results were compared with those obtained for 1-butene oxidation which indicated the most selective component of the catalyst for maleic anhydride formation was a MoO3 phase having a surface covering of NiMoO4; similar results were found to be applicable for 1,3-butadiene and furan oxidation. NiMoO44 was determined to be the catalyst component responsible for oxidative dehydrogenation of 1-butene; this phase also selectively blocked complete oxidation sites on MoO3, thereby changing the selectivity in favor of maleic anhydride.

AB - The selective oxidation of 1,3-butadiene and furan to maleic anhydride over NiMoO4 catalysts containing excess MoO3 was investigated. Activity and selectivity measurements were performed using a fixed-bed, integral reactor system. The results were compared with those obtained for 1-butene oxidation which indicated the most selective component of the catalyst for maleic anhydride formation was a MoO3 phase having a surface covering of NiMoO4; similar results were found to be applicable for 1,3-butadiene and furan oxidation. NiMoO44 was determined to be the catalyst component responsible for oxidative dehydrogenation of 1-butene; this phase also selectively blocked complete oxidation sites on MoO3, thereby changing the selectivity in favor of maleic anhydride.

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