Nitrogen quadrupole coupling and spin-rotation interaction in CH3NC

Research output: Contribution to journalArticle

12 Citations (Scopus)

Abstract

Hyperfine structure on the J = 1→0 transition in CH3NC was observed using a molecular beam maser spectrometer with 6 kHz resolution. Molecular parameters obtained from an analysis of the spectrum are: the nitrogen quadrupole coupling strength eqQ = (488.5±1.0) kHz, the nitrogen spin-rotation strength CN = (1.45±0.5) kHz, the hydrogen-hydrogen spin-spin interaction strength DHH = (21.33±0.5) kHz and the hydrogen spin-rotation strength CH = (-0.3±0.5) kHz.

Original languageEnglish (US)
Pages (from-to)52-55
Number of pages4
JournalChemical Physics Letters
Volume10
Issue number1
DOIs
StatePublished - Jul 1 1971
Externally publishedYes

Fingerprint

Hydrogen
Nitrogen
quadrupoles
nitrogen
Masers
Molecular beams
hydrogen
interactions
Spectrometers
masers
hyperfine structure
molecular beams
spectrometers
methylidyne

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Spectroscopy
  • Condensed Matter Physics
  • Atomic and Molecular Physics, and Optics
  • Surfaces and Interfaces

Cite this

Nitrogen quadrupole coupling and spin-rotation interaction in CH3NC. / Kukolich, Stephen G.

In: Chemical Physics Letters, Vol. 10, No. 1, 01.07.1971, p. 52-55.

Research output: Contribution to journalArticle

@article{4a220f12f5fa445383497dd5f4f92dc6,
title = "Nitrogen quadrupole coupling and spin-rotation interaction in CH3NC",
abstract = "Hyperfine structure on the J = 1→0 transition in CH3NC was observed using a molecular beam maser spectrometer with 6 kHz resolution. Molecular parameters obtained from an analysis of the spectrum are: the nitrogen quadrupole coupling strength eqQ = (488.5±1.0) kHz, the nitrogen spin-rotation strength CN = (1.45±0.5) kHz, the hydrogen-hydrogen spin-spin interaction strength DHH = (21.33±0.5) kHz and the hydrogen spin-rotation strength CH = (-0.3±0.5) kHz.",
author = "Kukolich, {Stephen G}",
year = "1971",
month = "7",
day = "1",
doi = "10.1016/0009-2614(71)80154-9",
language = "English (US)",
volume = "10",
pages = "52--55",
journal = "Chemical Physics Letters",
issn = "0009-2614",
publisher = "Elsevier",
number = "1",

}

TY - JOUR

T1 - Nitrogen quadrupole coupling and spin-rotation interaction in CH3NC

AU - Kukolich, Stephen G

PY - 1971/7/1

Y1 - 1971/7/1

N2 - Hyperfine structure on the J = 1→0 transition in CH3NC was observed using a molecular beam maser spectrometer with 6 kHz resolution. Molecular parameters obtained from an analysis of the spectrum are: the nitrogen quadrupole coupling strength eqQ = (488.5±1.0) kHz, the nitrogen spin-rotation strength CN = (1.45±0.5) kHz, the hydrogen-hydrogen spin-spin interaction strength DHH = (21.33±0.5) kHz and the hydrogen spin-rotation strength CH = (-0.3±0.5) kHz.

AB - Hyperfine structure on the J = 1→0 transition in CH3NC was observed using a molecular beam maser spectrometer with 6 kHz resolution. Molecular parameters obtained from an analysis of the spectrum are: the nitrogen quadrupole coupling strength eqQ = (488.5±1.0) kHz, the nitrogen spin-rotation strength CN = (1.45±0.5) kHz, the hydrogen-hydrogen spin-spin interaction strength DHH = (21.33±0.5) kHz and the hydrogen spin-rotation strength CH = (-0.3±0.5) kHz.

UR - http://www.scopus.com/inward/record.url?scp=34948896051&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=34948896051&partnerID=8YFLogxK

U2 - 10.1016/0009-2614(71)80154-9

DO - 10.1016/0009-2614(71)80154-9

M3 - Article

AN - SCOPUS:34948896051

VL - 10

SP - 52

EP - 55

JO - Chemical Physics Letters

JF - Chemical Physics Letters

SN - 0009-2614

IS - 1

ER -