Nonadiabatic effects in a method that combines classical and quantum mechanics

Dimitri Antoniou, Steven D. Schwartz

Research output: Contribution to journalArticle

20 Scopus citations

Abstract

We have included nonadiabatic effects in the calculation of the dynamical evolution of a system where a quantum particle in a double well is coupled to a classical oscillator. By performing an exponential resummation of the evolution operator we have included "polarization" effects (similar to the self-energy corrections for an electron that moves in a polarizable medium) which lead to a renormalizatiori of the energy of the quantum particle.

Original languageEnglish (US)
Pages (from-to)3526-3530
Number of pages5
JournalJournal of Chemical Physics
Volume104
Issue number10
DOIs
StatePublished - Jan 1 1996

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ASJC Scopus subject areas

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

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