We study the intramolecular proton transfer in the amino acid glycine in aqueous solution. We show that this system is an example of nonequilibrium solvation, where the proton-transfer step is fast and the solvent relaxes afterward. We show how the physical picture of equilibrium vs nonequilibrium solvation arises naturally within the framework of the quantized Zwanzig Hamiltonian. κ 2001 American Chemical Society.
|Original language||English (US)|
|Number of pages||5|
|Journal||Journal of Physical Chemistry A|
|State||Published - Mar 29 2001|
ASJC Scopus subject areas
- Physical and Theoretical Chemistry