Nonequilibrium sorption and transport of neutral and ionized chlorophenols

L. S. Lee, P. S C Rao, Mark L Brusseau

Research output: Chapter in Book/Report/Conference proceedingChapter

61 Citations (Scopus)

Abstract

For a series of chlorophenols sorption nonequilibrium was assessed by fitting a bicontinuum sorption model to breakthrough curves measured by miscible displacement techniques. A single log-log inverse relationship was observed between the desorption rate coefficient (k2,h-1) and the equilibrium sorption constant (Kp, mL/g) for all chlorophenols as well as for a series of chlorobenzenes. This suggests that approach to sorption equilibrium for neutral and ionized chlorophenols is constrained in a manner similar to that for nonpolar hydrophobic organic chemicals. -from Authors

Original languageEnglish (US)
Title of host publicationEnvironmental Science & Technology
Pages722-729
Number of pages8
Volume25
Edition4
StatePublished - 1991
Externally publishedYes

Fingerprint

Chlorophenols
chlorophenol
Sorption
sorption
Chlorobenzenes
Organic Chemicals
chlorobenzene
Organic chemicals
breakthrough curve
Desorption
desorption

ASJC Scopus subject areas

  • Environmental Science(all)
  • Earth and Planetary Sciences(all)
  • Environmental Engineering
  • Environmental Chemistry

Cite this

Lee, L. S., Rao, P. S. C., & Brusseau, M. L. (1991). Nonequilibrium sorption and transport of neutral and ionized chlorophenols. In Environmental Science & Technology (4 ed., Vol. 25, pp. 722-729)

Nonequilibrium sorption and transport of neutral and ionized chlorophenols. / Lee, L. S.; Rao, P. S C; Brusseau, Mark L.

Environmental Science & Technology. Vol. 25 4. ed. 1991. p. 722-729.

Research output: Chapter in Book/Report/Conference proceedingChapter

Lee, LS, Rao, PSC & Brusseau, ML 1991, Nonequilibrium sorption and transport of neutral and ionized chlorophenols. in Environmental Science & Technology. 4 edn, vol. 25, pp. 722-729.
Lee LS, Rao PSC, Brusseau ML. Nonequilibrium sorption and transport of neutral and ionized chlorophenols. In Environmental Science & Technology. 4 ed. Vol. 25. 1991. p. 722-729
Lee, L. S. ; Rao, P. S C ; Brusseau, Mark L. / Nonequilibrium sorption and transport of neutral and ionized chlorophenols. Environmental Science & Technology. Vol. 25 4. ed. 1991. pp. 722-729
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