Numerical Hartree-Fock study on the Rydberg-like excitations of He-2

Ludwik Adamowicz, Tadeusz Pluta

Research output: Contribution to journalArticle

14 Scopus citations

Abstract

Two new metastable states, 4Φg and 4Ig, of the He-2 anion are characterized using the numerical Hartree-Fock method. It is determined that such metastable quartet states are formed when the He+2 core attracts two electrons, which are placed into bonding orbitals, whose angular momentum quantum number differs by one.

Original languageEnglish (US)
Pages (from-to)517-523
Number of pages7
JournalChemical Physics Letters
Volume179
Issue number5-6
DOIs
StatePublished - May 3 1991

ASJC Scopus subject areas

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

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