Olefin metathesis for dendrimer assembly

Research output: Chapter in Book/Report/Conference proceedingChapter

Abstract

Conditions for the self-metathesis assembly of dendrons with alkenyl focal points into dendrimers are developed. Assembly of more complex central cores is the subject of current efforts. Olefin metathesis has become a powerful method in organic synthesis. Several ruthenium-based alkylidiene complexes have led to considerable success in the ring-opening metathesis and ring-closing metathesis reactions in application to the total synthesis of natural products. A preliminary study on the use of metathesis to assemble benzyl aryl ether dendrimers is reported. Self-metathesis yielding dendrimers is observed and the effects of solvent, temperature and reaction conditions on final product yield is optimized.

Original languageEnglish (US)
Title of host publicationAmerican Chemical Society, Polymer Preprints, Division of Polymer Chemistry
PublisherACS
Pages865
Number of pages1
Volume41
Edition1
StatePublished - Mar 2000
EventThe San Francisco Meeting - San Francisco, CA, USA
Duration: Mar 26 2000Mar 31 2000

Other

OtherThe San Francisco Meeting
CitySan Francisco, CA, USA
Period3/26/003/31/00

Fingerprint

Dendrimers
Alkenes
Olefins
Ruthenium
Self assembly
Ethers
Biological Products
Ether
Temperature

ASJC Scopus subject areas

  • Polymers and Plastics

Cite this

Li, S., & Mcgrath, D. V. (2000). Olefin metathesis for dendrimer assembly. In American Chemical Society, Polymer Preprints, Division of Polymer Chemistry (1 ed., Vol. 41, pp. 865). ACS.

Olefin metathesis for dendrimer assembly. / Li, Sheng; Mcgrath, Dominic V.

American Chemical Society, Polymer Preprints, Division of Polymer Chemistry. Vol. 41 1. ed. ACS, 2000. p. 865.

Research output: Chapter in Book/Report/Conference proceedingChapter

Li, S & Mcgrath, DV 2000, Olefin metathesis for dendrimer assembly. in American Chemical Society, Polymer Preprints, Division of Polymer Chemistry. 1 edn, vol. 41, ACS, pp. 865, The San Francisco Meeting, San Francisco, CA, USA, 3/26/00.
Li S, Mcgrath DV. Olefin metathesis for dendrimer assembly. In American Chemical Society, Polymer Preprints, Division of Polymer Chemistry. 1 ed. Vol. 41. ACS. 2000. p. 865
Li, Sheng ; Mcgrath, Dominic V. / Olefin metathesis for dendrimer assembly. American Chemical Society, Polymer Preprints, Division of Polymer Chemistry. Vol. 41 1. ed. ACS, 2000. pp. 865
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