Ozone oxidation of endocrine disruptors and pharmaceuticals in surface water and wastewater

Shane A. Snyder, Eric C. Wert, David J. Rexing, Ronald E. Zegers, Douglas D. Drury

Research output: Contribution to journalArticle

255 Scopus citations

Abstract

The oxidative removal of a diverse group of trace organic contaminants from surface water and wastewater was evaluated using ozone (O3) and O3 combined with hydrogen peroxide (O3/H2O 2). Target compounds included estrogenic and androgenic steroids, pharmaceuticals, pesticides, and industrial chemicals. Bench- and pilot- scale experiments were conducted with surface water spiked with the target compounds and wastewater effluent containing ambient concentrations of target compounds. Full-scale water treatment plants were sampled before and after ozonation to determine if bench- and pilot-scale results accurately predict full-scale removal. In both drinking water and wastewater experiments, the majority of target compounds were removed by greater than 90% at O3 exposures commonly used for disinfection. Atrazine, iopromide, meprobamate, and tris-chloroethylphosphate (TCEP) were the most recalcitrant compounds to oxidize using O3, with removals generally less than 50%. The addition of H2O2 for advanced oxidation was of little benefit for contaminant removal as compared to O3 alone. O3/H 2O2 provided a marginal increase in the removal of dilantin, diazepam, DEET, iopromide, and meprobamate, while decreasing the removal efficacy of pentoxifylline, caffeine, testosterone, progesterone, and androstenedione. In wastewater experiments, O3 and O 3/H2O2 were shown to remove in vitro estrogenicity. Collectively, these data provide evidence that O3 is a highly effective oxidant for removing the majority of trace organic contaminants from water.

Original languageEnglish (US)
Pages (from-to)445-460
Number of pages16
JournalOzone: Science and Engineering
Volume28
Issue number6
DOIs
StatePublished - Dec 1 2006
Externally publishedYes

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Keywords

  • Advanced Oxidation Process
  • Drinking Water
  • Endocrine Disruptors
  • Hydrogen Peroxide
  • Ozone
  • Pharmaceuticals
  • Surface Water
  • Wastewater
  • Water Reuse

ASJC Scopus subject areas

  • Environmental Engineering
  • Environmental Chemistry

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