Photo-induced structural changes in titanium alkoxides for directing molecular assembly

J. David Musgraves, Barrett G Potter, Robin M. Sewell, Timothy J. Boyle

Research output: Chapter in Book/Report/Conference proceedingConference contribution

1 Citation (Scopus)

Abstract

The effects of ultraviolet irradiation on a heteroleptic titanium alkoxide ((OPy)2Ti(4MP)2) have been investigated. The molecule has been studied in solution and in thin film form using FTIR and Raman spectroscopies. Quantum computational modeling was used to associate vibrational modes with structural moieties present in the molecule. In all cases examined, a preferential photoinduced modification in vibrational resonances linked to the 4-mercaptophenol (4MP) ligand was observed. In contrast, little or no change was exhibited in the vibrational structure of the OPy ligands.

Original languageEnglish (US)
Title of host publicationMaterials Research Society Symposium Proceedings
Pages131-136
Number of pages6
Volume960
StatePublished - 2007
Event2006 MRS Fall Meeting - Boston, MA, United States
Duration: Nov 27 2006Dec 1 2006

Other

Other2006 MRS Fall Meeting
CountryUnited States
CityBoston, MA
Period11/27/0612/1/06

Fingerprint

Titanium
Ligands
Molecules
Raman spectroscopy
Irradiation
Thin films
4-mercaptophenol

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials

Cite this

Musgraves, J. D., Potter, B. G., Sewell, R. M., & Boyle, T. J. (2007). Photo-induced structural changes in titanium alkoxides for directing molecular assembly. In Materials Research Society Symposium Proceedings (Vol. 960, pp. 131-136)

Photo-induced structural changes in titanium alkoxides for directing molecular assembly. / Musgraves, J. David; Potter, Barrett G; Sewell, Robin M.; Boyle, Timothy J.

Materials Research Society Symposium Proceedings. Vol. 960 2007. p. 131-136.

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Musgraves, JD, Potter, BG, Sewell, RM & Boyle, TJ 2007, Photo-induced structural changes in titanium alkoxides for directing molecular assembly. in Materials Research Society Symposium Proceedings. vol. 960, pp. 131-136, 2006 MRS Fall Meeting, Boston, MA, United States, 11/27/06.
Musgraves JD, Potter BG, Sewell RM, Boyle TJ. Photo-induced structural changes in titanium alkoxides for directing molecular assembly. In Materials Research Society Symposium Proceedings. Vol. 960. 2007. p. 131-136
Musgraves, J. David ; Potter, Barrett G ; Sewell, Robin M. ; Boyle, Timothy J. / Photo-induced structural changes in titanium alkoxides for directing molecular assembly. Materials Research Society Symposium Proceedings. Vol. 960 2007. pp. 131-136
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