Photodarkening in Ge3Se17 glass

Craig R. Schardt, Joseph H. Simmons, Pierre Lucas, Lydia Le Neindre, Jacques Lucas

Research output: Contribution to journalArticlepeer-review

28 Scopus citations

Abstract

In this paper, we present measurements of the kinetics of photodarkening in Ge3Se17 glass. The photodarkening is induced with sub-bandgap light and observed as transmission changes through a 1 mm thick sample of the glass. Both transient nonlinear and permanent processes are detected with these measurements. We consider the various sources that could lead to changes in sample optical properties and suggest that changes in electronic structure are the most reasonable explanation for the observed photodarkening. Comparison of the results with a model of light induced changes in amorphous selenium leads to an explanation for these effects based on the formation of dynamical bonds during illumination.

Original languageEnglish (US)
Pages (from-to)23-29
Number of pages7
JournalJournal of Non-Crystalline Solids
Volume274
Issue number1
DOIs
StatePublished - Sep 2000
Externally publishedYes

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Condensed Matter Physics
  • Materials Chemistry

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