Photoelectron imaging of carbonyl sulfide cluster anions: Isomer coexistence and competition of excited-state decay mechanisms

Eric Surber, Andrei M Sanov

Research output: Contribution to journalArticle

29 Citations (Scopus)

Abstract

An attempt was made to decipher the structure of (OCS)n- cluster anions using photoelectron spectroscopy. The employed imaging approach allowed the simultaneous examination of energy spectra and angular distributions of both fast and slow photoelectrons. The results provide evidence of the coexistence of electronic and structural isomers of (OCS)n- with the OCS- and covalently bound (OCS)2- cluster cores.

Original languageEnglish (US)
Pages (from-to)9192-9200
Number of pages9
JournalThe Journal of Chemical Physics
Volume118
Issue number20
DOIs
StatePublished - May 22 2003

Fingerprint

Angular distribution
Photoelectron spectroscopy
Photoelectrons
Excited states
Isomers
Anions
sulfides
photoelectrons
isomers
anions
Imaging techniques
decay
excitation
energy spectra
angular distribution
examination
photoelectron spectroscopy
electronics
carbonyl sulfide

ASJC Scopus subject areas

  • Atomic and Molecular Physics, and Optics

Cite this

Photoelectron imaging of carbonyl sulfide cluster anions : Isomer coexistence and competition of excited-state decay mechanisms. / Surber, Eric; Sanov, Andrei M.

In: The Journal of Chemical Physics, Vol. 118, No. 20, 22.05.2003, p. 9192-9200.

Research output: Contribution to journalArticle

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