Photoelectron imaging spectroscopy of molecular and cluster anions: CS2- and OCS- (H2O)1,2

Eric Surber, Andrei Sanov

Research output: Contribution to journalArticlepeer-review

68 Scopus citations

Abstract

Photoelectron imaging was used to study molecular and cluster anions on the examples of CS2- and OCS-(H2O)1,2. Results for OCS-(H2O)1,2 were compared to that of CS2-. The adiabatic electron affinity of OCS was estimated at -0.04 eV, while the VDEs of OCS-·H2 and OCS- were determined to be 2.07±0.07 and 2.53±0.07 eV, respectively.

Original languageEnglish (US)
Pages (from-to)5921-5924
Number of pages4
JournalJournal of Chemical Physics
Volume116
Issue number14
DOIs
StatePublished - Apr 8 2002

ASJC Scopus subject areas

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

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