Polymerization of trialkoxysilanes. Effect of the organic substituent on the formation of gels

Douglas A Loy, Brigitta M. Baugher, Duane A. Schneider

Research output: Chapter in Book/Report/Conference proceedingConference contribution

10 Citations (Scopus)

Abstract

The sol-gel chemistry of a variety of trialkoxysilanes with different organic substituents, with methoxide or ethoxide substituents on silicon was examined at varying monomer concentrations ranging up to neat monomer and with different catalysts. Gels were prepared from tetramethoxysilane and tetraethoxysilane at identical concentrations for purposes of comparison. The polymerization reactions were monitored for the formation of gels, insoluble precipitates, soluble polymers, or polyhedral oligosilsesquioxanes.

Original languageEnglish (US)
Title of host publicationAmerican Chemical Society, Polymer Preprints, Division of Polymer Chemistry
Editors Anon
PublisherACS
Pages418-419
Number of pages2
Volume39
Edition2
StatePublished - Aug 1998
Externally publishedYes
EventProceedings of the 1997 Boston Meeting - Boston, MA, USA
Duration: Aug 23 1998Aug 27 1998

Other

OtherProceedings of the 1997 Boston Meeting
CityBoston, MA, USA
Period8/23/988/27/98

Fingerprint

Gels
Monomers
Polymerization
Silicon
Polymers
Sol-gels
Precipitates
Catalysts
tetraethoxysilane
tetramethoxysilane

ASJC Scopus subject areas

  • Polymers and Plastics

Cite this

Loy, D. A., Baugher, B. M., & Schneider, D. A. (1998). Polymerization of trialkoxysilanes. Effect of the organic substituent on the formation of gels. In Anon (Ed.), American Chemical Society, Polymer Preprints, Division of Polymer Chemistry (2 ed., Vol. 39, pp. 418-419). ACS.

Polymerization of trialkoxysilanes. Effect of the organic substituent on the formation of gels. / Loy, Douglas A; Baugher, Brigitta M.; Schneider, Duane A.

American Chemical Society, Polymer Preprints, Division of Polymer Chemistry. ed. / Anon. Vol. 39 2. ed. ACS, 1998. p. 418-419.

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Loy, DA, Baugher, BM & Schneider, DA 1998, Polymerization of trialkoxysilanes. Effect of the organic substituent on the formation of gels. in Anon (ed.), American Chemical Society, Polymer Preprints, Division of Polymer Chemistry. 2 edn, vol. 39, ACS, pp. 418-419, Proceedings of the 1997 Boston Meeting, Boston, MA, USA, 8/23/98.
Loy DA, Baugher BM, Schneider DA. Polymerization of trialkoxysilanes. Effect of the organic substituent on the formation of gels. In Anon, editor, American Chemical Society, Polymer Preprints, Division of Polymer Chemistry. 2 ed. Vol. 39. ACS. 1998. p. 418-419
Loy, Douglas A ; Baugher, Brigitta M. ; Schneider, Duane A. / Polymerization of trialkoxysilanes. Effect of the organic substituent on the formation of gels. American Chemical Society, Polymer Preprints, Division of Polymer Chemistry. editor / Anon. Vol. 39 2. ed. ACS, 1998. pp. 418-419
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