Positive homotropic allosteric binding of silver(I) cations in a Schiff base oligopyrrolic macrocycle

Jonathan L. Sessler, Elisa Tomat, Vincent M. Lynch

Research output: Contribution to journalArticle

69 Citations (Scopus)

Abstract

The binuclear silver(I) complex of a Schiff base oligopyrrolic macrocycle was prepared in high yield and fully characterized. UV-visible absorption and 1H NMR spectroscopic analyses reveal that coordination of Ag(I) cations is subject to a strong positive homotropic allosteric effect.

Original languageEnglish (US)
Pages (from-to)4184-4185
Number of pages2
JournalJournal of the American Chemical Society
Volume128
Issue number13
DOIs
StatePublished - Apr 5 2006
Externally publishedYes

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Schiff Bases
Silver
Cations
Positive ions
Nuclear magnetic resonance
Proton Magnetic Resonance Spectroscopy

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

Positive homotropic allosteric binding of silver(I) cations in a Schiff base oligopyrrolic macrocycle. / Sessler, Jonathan L.; Tomat, Elisa; Lynch, Vincent M.

In: Journal of the American Chemical Society, Vol. 128, No. 13, 05.04.2006, p. 4184-4185.

Research output: Contribution to journalArticle

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