Positive homotropic allosteric binding of silver(I) cations in a Schiff base oligopyrrolic macrocycle

Jonathan L. Sessler, Elisa Tomat, Vincent M. Lynch

Research output: Contribution to journalArticle

74 Scopus citations

Abstract

The binuclear silver(I) complex of a Schiff base oligopyrrolic macrocycle was prepared in high yield and fully characterized. UV-visible absorption and 1H NMR spectroscopic analyses reveal that coordination of Ag(I) cations is subject to a strong positive homotropic allosteric effect.

Original languageEnglish (US)
Pages (from-to)4184-4185
Number of pages2
JournalJournal of the American Chemical Society
Volume128
Issue number13
DOIs
StatePublished - Apr 5 2006
Externally publishedYes

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

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