Quantitative correlation of absolute hydroxyl radical rate constants with non-isolated effluent organic matter bulk properties in water

Fernando L. Rosario-Ortiz, Stephen P. Mezyk, Devin F.R. Doud, Shane A. Snyder

Research output: Contribution to journalArticle

69 Scopus citations

Abstract

Absolute second-order rate constants for the reaction between the hydroxyl radical (OH) and eight water samples containing non-isolated effluent organic matter (EfOM) collected at different wastewater and reclamation sites were measured by electron pulse radiolysis. The measured rate constants ranged from 0.27 to 1.21 × 109 Mc-1 s-1, with an average value of 0.86 (±0.35) × 109 Mc -1 s-1. These absolute values were 3-5 times faster than previously reported values using natural organic matter and wastewater isolates. The obtained rate constants were correlated (R2 > 0.99) to bulk EfOM properties through an empirical equation that included terms relating to the polarity, apparent molecular weight, and fluorescence index of the effluent organic matter. The obtained data were used to model steady state OH concentrations during UV advanced oxidation. The steady-state OH concentration was lower than that obtained using previously reported values for the reaction with dissolved organic matter, indicating that accurate measurement of reaction rate constants at specific sites would greatly improve the design and prediction of the removal of organic contaminants. These results will improve the ability of researchers to accurately model scavenging capacities during the advanced oxidation process treatment of wastewaters.

Original languageEnglish (US)
Pages (from-to)5924-5930
Number of pages7
JournalEnvironmental Science and Technology
Volume42
Issue number16
DOIs
StatePublished - Aug 15 2008
Externally publishedYes

ASJC Scopus subject areas

  • Chemistry(all)
  • Environmental Chemistry

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