Raman scattering study of the Ba1-xRxF2+x superionic conductors

Miroslav Kolesik, B. P. Sobolev

Research output: Contribution to journalArticle

5 Citations (Scopus)

Abstract

The nonstoichiometric solid solutions Ba1-xRxF2+x (where R = Ce, Pr, Gd, Tb; and 0.10≤x≤0.30) are studied by Raman spectroscopy. Besides the main Raman peak, two additional bands are observed on its high-frequency side. A new interpretation for the extra-peaks, based on the cluster structure, is proposed. The observed vibrations seem to be connected with 8:12: (0, 1, 2) clusters.

Original languageEnglish (US)
Pages (from-to)325-329
Number of pages5
JournalSolid State Ionics
Volume47
Issue number3-4
DOIs
StatePublished - 1991
Externally publishedYes

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Raman spectroscopy
Raman scattering
Solid solutions
conductors
Raman spectra
solid solutions
vibration

ASJC Scopus subject areas

  • Electrochemistry
  • Physical and Theoretical Chemistry
  • Energy Engineering and Power Technology
  • Materials Chemistry
  • Condensed Matter Physics

Cite this

Raman scattering study of the Ba1-xRxF2+x superionic conductors. / Kolesik, Miroslav; Sobolev, B. P.

In: Solid State Ionics, Vol. 47, No. 3-4, 1991, p. 325-329.

Research output: Contribution to journalArticle

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