REACTIONS OF CLEAN LITHIUM SURFACES WITH SO//2: MOLECULAR AUGER LINE-SHAPE ANALYSIS AND REACTION KINETICS.

Kenneth W. Nebesny, Neal R Armstrong

Research output: Contribution to journalArticle

8 Citations (Scopus)

Abstract

The products of the reaction of SO//2 with clean metal surfaces have been examined using Auger electron spectroscopy. The Auger spectra were deconvolved of sample and instrument broadening effects, which allowed for detailed fingerprint spectra of several sulfur oxyanions to be distinguished. The rate of reaction of SO//2 with the clean Li metal (at low surface coverages) was measured for temperatures between 298 and 357 K. An activation energy of 2-5 kcal/mol was determined for the initial reaction to form the Li//2S/Li//2O monolayer. A model for the growth and stability of the layer is presented.

Original languageEnglish (US)
Pages (from-to)469-477
Number of pages9
JournalLangmuir
Volume1
Issue number4
StatePublished - Jul 1985

Fingerprint

Lithium
Reaction kinetics
line shape
reaction kinetics
lithium
Metals
kinetics
Auger electron spectroscopy
Sulfur
Monolayers
Activation energy
Auger spectroscopy
metal surfaces
electron spectroscopy
sulfur
activation energy
products
metals
Temperature
temperature

ASJC Scopus subject areas

  • Colloid and Surface Chemistry
  • Physical and Theoretical Chemistry

Cite this

REACTIONS OF CLEAN LITHIUM SURFACES WITH SO//2 : MOLECULAR AUGER LINE-SHAPE ANALYSIS AND REACTION KINETICS. / Nebesny, Kenneth W.; Armstrong, Neal R.

In: Langmuir, Vol. 1, No. 4, 07.1985, p. 469-477.

Research output: Contribution to journalArticle

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