Regioselective N/C-heterocyclization of allenylindium bromide across aryl azides: One-pot synthesis of 5-methyl-1,2,3-triazoles

Abid H. Banday, Victor J. Hruby

Research output: Contribution to journalArticle

4 Scopus citations

Abstract

An unprecedented, one-pot regioselective synthesis of 1,5-disubstituted 1,2,3-triazoles through N/C-heterocyclization of allenylindium bromide across aryl azides is described. The synthesis is carried out under mild conditions in aqueous medium and proceeds regioselectively in moderate to good yields.

Original languageEnglish (US)
Article numberst-2014-r0218-l
Pages (from-to)1859-1862
Number of pages4
JournalSynlett
Volume25
Issue number13
DOIs
StatePublished - Aug 2014

Keywords

  • 1,2,3-triazoles
  • allenylindium bromide
  • aryl azides
  • heterocyclization
  • regioselective reactions

ASJC Scopus subject areas

  • Organic Chemistry

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