Relative strengths of early transition metal M-H and M-C bonds in substituted niobocenes and tantalocenes. Thermodynamic trends and electronic factors of olefin insertion into a metal-hydride bond

Dennis L Lichtenberger, Gary P. Darsey, Glen Eugene Kellogg, Robert D. Sanner, Victor G. Young, James R. Clark

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Abstract

Principles of M-C and M-H bonding interactions are examined experimentally by high-resolution valence photoelectron spectroscopy. Gas-phase He I and He II photoelectron spectra are reported for the following series of d0 and d2 bent metallocenes: Cp2MH3 (M = Nb, Ta), Cp2M(CO)L (M = Nb, Ta; L = H and M = Nb; L = CH3), and Cp2M(C2H4)L (M = Nb, Ta; L = H and M = Ta; L = C2H5) (Cp = η5-C5H5). The ligand replacements represented by this series of complexes allow stepwise comparison and assignment of each individual low-energy valence ionization band. The He I/He II spectral comparisons show that the lowest ionization energy band of the carbonyl complexes is higher in metal character than the corresponding ionization of the ethylene complexes. This trend indicates extensive electron delocalization in the metal-ethylene bonding that corresponds more accurately to a metallacyclopropane description with relatively strong metal-carbon bonds. The photoelectron data for the early transition metal hydride and alkyl species show that the metal-hydrogen bonds are slightly more stable than the metal-carbon bonds. Correlation of the ionization information for these substituted early metallocenes reveals that the stabilization of the metallacyclopropane-hydride structures, M(C2H4)H, relative to the olefin-inserted metal-alkyl structure, M(C2H5), is partly due to stabilization of the metal electron density by back-bonding to the olefin as indicated by earlier theoretical studies. However, this factor alone is not sufficient to offset the energy required to convert a carbon-hydrogen bond in M(C2H5) to a metal-hydrogen bond in M(C2H4)H. The additional important factor is the stabilization derived from conversion of the metal-alkyl σ bonding to the more favorable delocalized M-C2 σ-bonding situation in the metallacyclopropane hydride.

Original languageEnglish (US)
Pages (from-to)5019-5028
Number of pages10
JournalJournal of the American Chemical Society
Volume111
Issue number14
StatePublished - 1989

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Alkenes
Thermodynamics
Hydrides
Olefins
Transition metals
Metals
Ionization
Hydrogen bonds
Carbon
Stabilization
Hydrogen
Organometallics
Photoelectrons
Ethylene
Electrons
Ionization potential
Photoelectron Spectroscopy
Carbon Monoxide
Photoelectron spectroscopy
Band structure

ASJC Scopus subject areas

  • Chemistry(all)

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Relative strengths of early transition metal M-H and M-C bonds in substituted niobocenes and tantalocenes. Thermodynamic trends and electronic factors of olefin insertion into a metal-hydride bond. / Lichtenberger, Dennis L; Darsey, Gary P.; Kellogg, Glen Eugene; Sanner, Robert D.; Young, Victor G.; Clark, James R.

In: Journal of the American Chemical Society, Vol. 111, No. 14, 1989, p. 5019-5028.

Research output: Contribution to journalArticle

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abstract = "Principles of M-C and M-H bonding interactions are examined experimentally by high-resolution valence photoelectron spectroscopy. Gas-phase He I and He II photoelectron spectra are reported for the following series of d0 and d2 bent metallocenes: Cp2MH3 (M = Nb, Ta), Cp2M(CO)L (M = Nb, Ta; L = H and M = Nb; L = CH3), and Cp2M(C2H4)L (M = Nb, Ta; L = H and M = Ta; L = C2H5) (Cp = η5-C5H5). The ligand replacements represented by this series of complexes allow stepwise comparison and assignment of each individual low-energy valence ionization band. The He I/He II spectral comparisons show that the lowest ionization energy band of the carbonyl complexes is higher in metal character than the corresponding ionization of the ethylene complexes. This trend indicates extensive electron delocalization in the metal-ethylene bonding that corresponds more accurately to a metallacyclopropane description with relatively strong metal-carbon bonds. The photoelectron data for the early transition metal hydride and alkyl species show that the metal-hydrogen bonds are slightly more stable than the metal-carbon bonds. Correlation of the ionization information for these substituted early metallocenes reveals that the stabilization of the metallacyclopropane-hydride structures, M(C2H4)H, relative to the olefin-inserted metal-alkyl structure, M(C2H5), is partly due to stabilization of the metal electron density by back-bonding to the olefin as indicated by earlier theoretical studies. However, this factor alone is not sufficient to offset the energy required to convert a carbon-hydrogen bond in M(C2H5) to a metal-hydrogen bond in M(C2H4)H. The additional important factor is the stabilization derived from conversion of the metal-alkyl σ bonding to the more favorable delocalized M-C2 σ-bonding situation in the metallacyclopropane hydride.",
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T1 - Relative strengths of early transition metal M-H and M-C bonds in substituted niobocenes and tantalocenes. Thermodynamic trends and electronic factors of olefin insertion into a metal-hydride bond

AU - Lichtenberger, Dennis L

AU - Darsey, Gary P.

AU - Kellogg, Glen Eugene

AU - Sanner, Robert D.

AU - Young, Victor G.

AU - Clark, James R.

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N2 - Principles of M-C and M-H bonding interactions are examined experimentally by high-resolution valence photoelectron spectroscopy. Gas-phase He I and He II photoelectron spectra are reported for the following series of d0 and d2 bent metallocenes: Cp2MH3 (M = Nb, Ta), Cp2M(CO)L (M = Nb, Ta; L = H and M = Nb; L = CH3), and Cp2M(C2H4)L (M = Nb, Ta; L = H and M = Ta; L = C2H5) (Cp = η5-C5H5). The ligand replacements represented by this series of complexes allow stepwise comparison and assignment of each individual low-energy valence ionization band. The He I/He II spectral comparisons show that the lowest ionization energy band of the carbonyl complexes is higher in metal character than the corresponding ionization of the ethylene complexes. This trend indicates extensive electron delocalization in the metal-ethylene bonding that corresponds more accurately to a metallacyclopropane description with relatively strong metal-carbon bonds. The photoelectron data for the early transition metal hydride and alkyl species show that the metal-hydrogen bonds are slightly more stable than the metal-carbon bonds. Correlation of the ionization information for these substituted early metallocenes reveals that the stabilization of the metallacyclopropane-hydride structures, M(C2H4)H, relative to the olefin-inserted metal-alkyl structure, M(C2H5), is partly due to stabilization of the metal electron density by back-bonding to the olefin as indicated by earlier theoretical studies. However, this factor alone is not sufficient to offset the energy required to convert a carbon-hydrogen bond in M(C2H5) to a metal-hydrogen bond in M(C2H4)H. The additional important factor is the stabilization derived from conversion of the metal-alkyl σ bonding to the more favorable delocalized M-C2 σ-bonding situation in the metallacyclopropane hydride.

AB - Principles of M-C and M-H bonding interactions are examined experimentally by high-resolution valence photoelectron spectroscopy. Gas-phase He I and He II photoelectron spectra are reported for the following series of d0 and d2 bent metallocenes: Cp2MH3 (M = Nb, Ta), Cp2M(CO)L (M = Nb, Ta; L = H and M = Nb; L = CH3), and Cp2M(C2H4)L (M = Nb, Ta; L = H and M = Ta; L = C2H5) (Cp = η5-C5H5). The ligand replacements represented by this series of complexes allow stepwise comparison and assignment of each individual low-energy valence ionization band. The He I/He II spectral comparisons show that the lowest ionization energy band of the carbonyl complexes is higher in metal character than the corresponding ionization of the ethylene complexes. This trend indicates extensive electron delocalization in the metal-ethylene bonding that corresponds more accurately to a metallacyclopropane description with relatively strong metal-carbon bonds. The photoelectron data for the early transition metal hydride and alkyl species show that the metal-hydrogen bonds are slightly more stable than the metal-carbon bonds. Correlation of the ionization information for these substituted early metallocenes reveals that the stabilization of the metallacyclopropane-hydride structures, M(C2H4)H, relative to the olefin-inserted metal-alkyl structure, M(C2H5), is partly due to stabilization of the metal electron density by back-bonding to the olefin as indicated by earlier theoretical studies. However, this factor alone is not sufficient to offset the energy required to convert a carbon-hydrogen bond in M(C2H5) to a metal-hydrogen bond in M(C2H4)H. The additional important factor is the stabilization derived from conversion of the metal-alkyl σ bonding to the more favorable delocalized M-C2 σ-bonding situation in the metallacyclopropane hydride.

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