Repeated reductive and oxidative treatments of granular activated carbon

Scott G. Huling, Patrick K. Jones, Wendell P Ela, Robert G Arnold

Research output: Contribution to journalArticle

20 Citations (Scopus)

Abstract

Fenton oxidation and reductive treatment solutions were applied to granular activated carbon (GAC) to chemically regenerate the adsorbent. No adsorbate was present on the GAC so physicochemical effects from chemically aggressive regeneration could be distinguished from the potential effects of accumulation of reaction byproducts. Fifteen sequential oxidation treatments with hydrogen peroxide (H2O2) and fifteen sequential reduction/oxidation treatments with hydroxylamine and H2O2 on Fe-amended GAC were evaluated. The GAC Iodine number, N2 Brunauer-Emmett-Teller surface area, microporosity, and total porosity declined with sequential treatments, but meso- and macroporosity essentially remained unchanged. Similar changes in Iodine number, surface area, and pore volume distribution suggest that the effects of treatment are functionally dependent on oxidation and independent of hydroxylamine reduction. An inverse relationship was established between the number of chemical treatments and contaminant (methyl tert-butyl ether, 2-chlorophenol, trichloroethylene) adsorption. Loss in sorptive capacity was attributed to the combined and undifferentiated effects of reductions in microporosity and surface area, alterations in surface chemistry (overabundance of surface oxides), and to a lesser degree, micropore blockage by iron oxides.

Original languageEnglish (US)
Pages (from-to)287-297
Number of pages11
JournalJournal of Environmental Engineering
Volume131
Issue number2
DOIs
StatePublished - Feb 2005

Fingerprint

Activated carbon
activated carbon
Oxidation
Microporosity
Hydroxylamine
surface area
iodine
Iodine
oxidation
Trichloroethylene
MTBE
chlorophenol
Adsorbates
trichloroethylene
Surface chemistry
Iron oxides
Hydrogen peroxide
iron oxide
Adsorbents
Oxides

Keywords

  • Activated carbon
  • Adsorption
  • Hydrogen peroxide
  • Organic chemicals
  • Oxidation

ASJC Scopus subject areas

  • Environmental Engineering
  • Environmental Science(all)
  • Environmental Chemistry
  • Civil and Structural Engineering

Cite this

Repeated reductive and oxidative treatments of granular activated carbon. / Huling, Scott G.; Jones, Patrick K.; Ela, Wendell P; Arnold, Robert G.

In: Journal of Environmental Engineering, Vol. 131, No. 2, 02.2005, p. 287-297.

Research output: Contribution to journalArticle

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