ROTATING DISK CELL FOR RAMAN SPECTROELECTROCHEMISTRY: INVESTIGATION OF AN ELECTRODE SURFACE SPECIES AND AN ELECTROGENERATED SOLUTION SPECIES.

Jeanne E. Pemberton, Richard P. Buck

Research output: Contribution to journalArticle

30 Scopus citations

Abstract

A Raman spectroelectrochemical cell has been developed which incorporates a rotating disk design. This cell has been shown to be useful for the Raman investigation of electrode surface species (spinning electrode) and electrogenerated solution species (static electrode). It has been used to characterize the Raman spectroelectrochemical behavior of photolabile dithizone anion adsorbed at silver and copper electrode surfaces. Use of this cell for the study of electrogenerated solution species was demonstrated by the resonance Raman characterization of the tetracyanoethylene anion radical electrogenerated with a cyclic potential step. Cell construction is described and its merits discussed.

Original languageEnglish (US)
Pages (from-to)571-576
Number of pages6
JournalApplied Spectroscopy
Volume35
Issue number6
DOIs
StatePublished - Jan 1 1981
Externally publishedYes

ASJC Scopus subject areas

  • Instrumentation
  • Spectroscopy

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