TY - JOUR
T1 - ROTATING DISK CELL FOR RAMAN SPECTROELECTROCHEMISTRY
T2 - INVESTIGATION OF AN ELECTRODE SURFACE SPECIES AND AN ELECTROGENERATED SOLUTION SPECIES.
AU - Pemberton, Jeanne E.
AU - Buck, Richard P.
PY - 1981/1/1
Y1 - 1981/1/1
N2 - A Raman spectroelectrochemical cell has been developed which incorporates a rotating disk design. This cell has been shown to be useful for the Raman investigation of electrode surface species (spinning electrode) and electrogenerated solution species (static electrode). It has been used to characterize the Raman spectroelectrochemical behavior of photolabile dithizone anion adsorbed at silver and copper electrode surfaces. Use of this cell for the study of electrogenerated solution species was demonstrated by the resonance Raman characterization of the tetracyanoethylene anion radical electrogenerated with a cyclic potential step. Cell construction is described and its merits discussed.
AB - A Raman spectroelectrochemical cell has been developed which incorporates a rotating disk design. This cell has been shown to be useful for the Raman investigation of electrode surface species (spinning electrode) and electrogenerated solution species (static electrode). It has been used to characterize the Raman spectroelectrochemical behavior of photolabile dithizone anion adsorbed at silver and copper electrode surfaces. Use of this cell for the study of electrogenerated solution species was demonstrated by the resonance Raman characterization of the tetracyanoethylene anion radical electrogenerated with a cyclic potential step. Cell construction is described and its merits discussed.
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U2 - 10.1366/0003702814732238
DO - 10.1366/0003702814732238
M3 - Article
AN - SCOPUS:0019634473
VL - 35
SP - 571
EP - 576
JO - Applied Spectroscopy
JF - Applied Spectroscopy
SN - 0003-7028
IS - 6
ER -