Rotational spectroscopy of ClZnCH3 (X1A1): Gas-phase synthesis and characterization of a monomeric Grignard-type reagent

J. Min, M. P. Bucchino, K. M. Kilchenstein, L. M. Ziurys

Research output: Contribution to journalArticle

2 Scopus citations

Abstract

The pure rotational spectrum of the organozinc halide, ClZnCH3 (X1A1), has been measured using Fourier-transform microwave (FTMW) and millimeter-wave direct-absorption methods in the frequency range 10-296 GHz. This work is the first study of ClZnCH3 by gas-phase spectroscopy. The molecule was created in a DC discharge from the reaction of zinc vapor, produced either by a Broida-type oven or by laser ablation, with chloromethane in what appears to be a metal insertion process. Rotational and chlorine quadrupole constants were determined for three zinc isotopologues. The Zn-Cl bond was found to be partly ionic and significantly shorter than in EtZnCl.

Original languageEnglish (US)
Pages (from-to)174-178
Number of pages5
JournalChemical Physics Letters
Volume646
DOIs
StatePublished - Feb 16 2016

ASJC Scopus subject areas

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

Fingerprint Dive into the research topics of 'Rotational spectroscopy of ClZnCH<sub>3</sub> (X<sup>1</sup>A<sub>1</sub>): Gas-phase synthesis and characterization of a monomeric Grignard-type reagent'. Together they form a unique fingerprint.

  • Cite this